Opálková Šišková Alena, Dvorák Tomáš, Šimonová Baranyaiová Tímea, Šimon Erik, Eckstein Andicsová Anita, Švajdlenková Helena, Opálek Andrej, Krížik Peter, Nosko Martin
Institute of Materials and Machine Mechanics, Slovak Academy of Sciences, Dúbravská cesta 9, 84513 Bratislava, Slovakia.
Polymer Institute of Slovak Academy of Sciences, Dúbravská cesta 9, 84541 Bratislava, Slovakia.
Materials (Basel). 2020 Nov 28;13(23):5424. doi: 10.3390/ma13235424.
The current study reflects the demand to mitigate the environmental issues caused by the waste from the agriculture and food industry. The crops that do not meet the supply chain requirements and waste from their processing are overfilling landfills. The mentioned wastes contain cellulose, which is the most abundant carbon precursor. Therefore, one of the possibilities of returning such waste into the life cycle could be preparing the activated carbon through an eco-friendly and simple route. Herein, the carrot pulp from the waste was used. Techniques such as thermogravimetric analysis (TGA), elemental analysis (EA), scanning electron microscopy (SEM), Fourier-transform infrared spectroscopy (FTIR), Raman spectroscopy, and x-ray diffraction (XRD) were used to investigate the thermal treatment effect during the carbon material preparation. The development of microstructure, phase formation, and chemical composition of prepared material was evaluated. The obtained carbon material was finally tested for water cleaning from a synthetic pollutant such as rhodamine B and phloxine B. An adsorption mechanism was proposed on the base of positron annihilation lifetime spectroscopy (PALS) results and attributed to the responsible interactions. It was shown that a significant carbon sorbent from the organic waste for water purification was obtained.
当前的研究反映了减轻农业和食品工业废弃物所造成环境问题的需求。不符合供应链要求的农作物及其加工过程中产生的废弃物,正使垃圾填埋场不堪重负。上述废弃物含有纤维素,而纤维素是最丰富的碳前驱体。因此,通过一种环保且简单的途径制备活性炭,可能是将此类废弃物重新纳入生命周期的一种方式。在此,使用了来自废弃物的胡萝卜渣。热重分析(TGA)、元素分析(EA)、扫描电子显微镜(SEM)、傅里叶变换红外光谱(FTIR)、拉曼光谱和X射线衍射(XRD)等技术,用于研究碳材料制备过程中的热处理效果。评估了所制备材料的微观结构发展、相形成和化学成分。最终对所得碳材料进行了从罗丹明B和玫瑰红B等合成污染物中净化水的测试。基于正电子湮没寿命谱(PALS)结果提出了吸附机制,并归因于相关相互作用。结果表明,从有机废弃物中获得了一种用于水净化的高效碳吸附剂。