Naraghi Behnaz, Zabihi Fahimeh, Narooie Mohammad Reza, Saeidi Mahdi, Biglari Hamed
MSc. of Environmental Health, Senior Lecturer, Department of Environmental Health Engineering, School of Public Health, Birjand University of Medical Sciences, Birjand, Iran.
MSc. of Environmental Health, Senior Lecturer, Department of Environmental Health Engineering, School of Public Health, Iranshahr University of Medical Sciences, Iranshahr, Iran.
Electron Physician. 2017 May 25;9(5):4312-4321. doi: 10.19082/4312. eCollection 2017 May.
Water resources pollution control is one of the main challenges of our time for researchers. Colored wastewater discharges caused by textile industry activities has added to the concern. In this study, removal of Acid Orange 7 dye (AO7) using Kenya Tea residue absorbent (granular) has been studied.
This cross-sectional study was conducted in 2016. In this work, initially, tea residue was prepared in three forms of raw, treated with concentrated phosphoric acid, and carbonated, at temperatures of 350, 450 and 500 °C in the chemistry laboratory of Gonabad University of Medical Sciences. Then, efficiency of the above absorbents in the removal of Acid Orange 7 dye in initial concentrations of dye as 50-500 mg/l from water samples in terms of pH 2-10 and 1-10 g/l of adsorbent dose within 20 to 300 minutes was investigated. In addition, their subordination from Langmuir and Freundlich absorption isotherms was also determined. Concentration changes in Acid Orange 7 dye at a wavelength of 483 nm was determined by spectrophotometry and results were reported using descriptive statistics.
Results showed that efficiency of Acid Orange 7 dye removal is higher in acidic pH and higher adsorbent dosage. The highest efficiency of Acid Orange 7 dye removal was 98.41% by raw tea residue absorbent at pH 2, reaction time was 120 minutes and initial concentration of dye was 50 mg/l, which was obtained at adsorbent dosage of 10 g/l. It was determined that the mechanism of absorption acceptably follows Freundlich absorption isotherm (R=0.97).
Due to the availability and very low price, optimal performance of Kenya tea raw residue (granular) in Acid Orange 7 dye removal, it can be used as an efficient surface absorber in an absorber from colored wastewater.
水资源污染控制是当今研究人员面临的主要挑战之一。纺织工业活动导致的有色废水排放加剧了这一担忧。本研究对使用肯尼亚茶渣吸附剂(颗粒状)去除酸性橙7染料(AO7)进行了研究。
本横断面研究于2016年开展。在这项工作中,最初,在戈纳巴德医科大学化学实验室中,将茶渣制备成三种形式:原样、用浓磷酸处理以及碳酸化,温度分别为350、450和500℃。然后,研究了上述吸附剂在pH值为2 - 10、吸附剂剂量为1 - 10 g/l的条件下,对初始浓度为50 - 500 mg/l的水样中酸性橙7染料的去除效率,反应时间为20至300分钟。此外,还确定了它们对朗缪尔和弗伦德利希吸附等温线的拟合情况。通过分光光度法测定酸性橙7染料在483 nm波长处的浓度变化,并使用描述性统计报告结果。
结果表明,在酸性pH值和较高吸附剂用量条件下,酸性橙7染料的去除效率更高。原样茶渣吸附剂在pH值为2、反应时间为120分钟、染料初始浓度为50 mg/l、吸附剂用量为10 g/l时,酸性橙7染料的最高去除效率为98.41%。确定吸附机制符合弗伦德利希吸附等温线(R = 0.97)。
由于肯尼亚茶原样残渣(颗粒状)易于获取且价格极低,在去除酸性橙7染料方面表现出最佳性能,因此可作为一种高效的表面吸附剂用于处理有色废水。