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具有钆和锡共掺杂铋铁氧体的二维MXene纳米杂化物的高效可见光光催化作用

Efficient Visible-Light Photocatalysis of 2D-MXene Nanohybrids with Gd- and Sn-Codoped Bismuth Ferrite.

作者信息

Tariq Ayesha, Ali S Irfan, Akinwande Deji, Rizwan Syed

机构信息

Department of Physics, School of Natural Sciences (SNS), National University of Sciences and Technology (NUST), Islamabad 44000, Pakistan.

Shenzhen Key Laboratory of Advanced Thin Films and Applications, College of Physics and Energy and Key Laboratory of Optoelectronic Devices and Systems of Ministry of Education and Guangdong Province, College of Optoelectronic Engineering, Shenzhen University, Shenzhen 518060, China.

出版信息

ACS Omega. 2018 Oct 22;3(10):13828-13836. doi: 10.1021/acsomega.8b01951. eCollection 2018 Oct 31.

Abstract

Nowadays, photocatalysis has gained tremendous interest owing to the fact that it can overcome water crisis as well as the environmental issues by utilizing a major source of solar energy. The nanohybrid structures of Gd- and Sn-doped bismuth ferrite (Bi Gd Fe Sn ; BGFSO) with two-dimensional (2D) MXene sheets are synthesized by the coprecipitation method. The 2D sheets have a large surface area, incorporation of which into Bi Gd Fe Sn (BGFSO) nanoparticles provides a path for electrons to flow, which results in large recombination time and thus enhances dye degradation. The BiGdFeSnO/MXene (BGFO-20Sn/MXene) nanohybrid shows 100% degradation of Congo dye from the catalytic solution in 120 min, which is highly efficient for industrial application.

摘要

如今,光催化因其能够利用太阳能这一主要能源来克服水危机以及环境问题而备受关注。采用共沉淀法合成了具有二维(2D)MXene片层的钆(Gd)和锡(Sn)掺杂的铋铁氧体(BiGdFeSn;BGFSO)纳米杂化结构。二维片层具有较大的表面积,将其掺入BiGdFeSn(BGFSO)纳米颗粒中为电子流动提供了一条路径,这导致了较长的复合时间,从而增强了染料降解。BiGdFeSnO/MXene(BGFO-20Sn/MXene)纳米杂化物在120分钟内可使催化溶液中的刚果染料100%降解,这对于工业应用而言效率极高。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6330/6645294/fc93624b000b/ao-2018-01951n_0001.jpg

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