由[Mn(BH)·3THF]·NaBH合成锰基金属有机框架材料ZIF-8 。
Synthesis of Manganese ZIF-8 from [Mn(BH)·3THF]·NaBH.
作者信息
Kadota Kentaro, Sivaniah Easan, Bureekaew Sareeya, Kitagawa Susumu, Horike Satoshi
机构信息
Institute for Integrated Cell-Material Sciences (WPI-iCeMS), Institute for Advanced Study, Kyoto University , Yoshida, Sakyo-ku, Kyoto 606-8501, Japan.
Department of Chemical and Biomolecular Engineering, School of Energy Science and Engineering, Vidyasirimedhi Institute of Science and Technology , Rayong 21210, Thailand.
出版信息
Inorg Chem. 2017 Aug 7;56(15):8744-8747. doi: 10.1021/acs.inorgchem.7b01322. Epub 2017 Jul 17.
Cubic and highly porous [Mn(2-methylimidazolate)] (Mn-ZIF-8) was synthesized from [Mn(BH)·3THF]·NaBH under an Ar atmosphere. The structure contains rare Mn-4N tetrahedral geometry and has larger cell parameters, resulting in 20% larger amounts of gas uptake compared with [Zn(2-methylimidazolate)]. A kinetically favored reaction using a reactive metal borohydride precursor is key for the construction of new metal-organic framework systems.
立方且具有高度多孔性的[Mn(2-甲基咪唑)]（Mn-ZIF-8）是在氩气氛围下由[Mn(BH)·3THF]·NaBH合成的。该结构包含罕见的Mn-4N四面体几何结构，且具有更大的晶胞参数，与[Zn(2-甲基咪唑)]相比，气体吸收量增加了20%。使用活性金属硼氢化物前驱体进行动力学有利的反应是构建新型金属有机框架体系的关键。
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