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Elongation of magnetic relaxation times in a single-molecule magnet through intermetallic interactions: a clamshell-type dinuclear terbium(iii)-phthalocynaninato quadruple-decker complex.

作者信息

Horii Yoji, Katoh Keiichi, Breedlove Brian K, Yamashita Masahiro

机构信息

Department of Chemistry, Graduate School of Science, Tohoku University, 6-3, Aramaki-Aza-Aoba, Aoba-ku, Sendai 980-8578, Japan.

出版信息

Chem Commun (Camb). 2017 Jul 27;53(61):8561-8564. doi: 10.1039/c7cc03553e.

DOI:10.1039/c7cc03553e
PMID:28715027
Abstract

A clamshell-type terbium(iii)-phthalocyaninato quadruple-decker complex was synthesized. Magnetic measurements revealed that Tb-Tb interactions caused an increase in the magnetic relaxation time and enhanced the SMM properties.

摘要

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