Li Yuanyuan, Fu Qiliang, Rojas Ramiro, Yan Min, Lawoko Martin, Berglund Lars
Department of Fibre and Polymer Technology, Wallenberg Wood Science Center, Chemical Science and Engineering Institution, KTH Royal Institute of Technology, Teknikringen 56-58, Stockholm, Sweden.
School of Engineering Sciences, KTH Royal Institute of Technology, Isafjordsgatan 22, Stockholm, Sweden.
ChemSusChem. 2017 Sep 11;10(17):3445-3451. doi: 10.1002/cssc.201701089. Epub 2017 Aug 9.
Optically transparent wood, combining optical and mechanical performance, is an emerging new material for light-transmitting structures in buildings with the aim of reducing energy consumption. One of the main obstacles for transparent wood fabrication is delignification, where around 30 wt % of wood tissue is removed to reduce light absorption and refractive index mismatch. This step is time consuming and not environmentally benign. Moreover, lignin removal weakens the wood structure, limiting the fabrication of large structures. A green and industrially feasible method has now been developed to prepare transparent wood. Up to 80 wt % of lignin is preserved, leading to a stronger wood template compared to the delignified alternative. After polymer infiltration, a high-lignin-content transparent wood with transmittance of 83 %, haze of 75 %, thermal conductivity of 0.23 W mK , and work-tofracture of 1.2 MJ m (a magnitude higher than glass) was obtained. This transparent wood preparation method is efficient and applicable to various wood species. The transparent wood obtained shows potential for application in energy-saving buildings.
光学透明木材兼具光学和机械性能,是一种新兴的用于建筑透光结构的新材料,旨在降低能源消耗。透明木材制造的主要障碍之一是脱木质素,即去除约30 wt%的木材组织以减少光吸收和折射率失配。这一步既耗时又不环保。此外,去除木质素会削弱木材结构,限制大型结构的制造。现在已经开发出一种绿色且工业上可行的方法来制备透明木材。保留了高达80 wt%的木质素,与脱木质素的木材相比,形成了更强的木材模板。聚合物渗透后,得到了一种高木质素含量的透明木材,其透光率为83%,雾度为75%,热导率为0.23 W mK,断裂功为1.2 MJ m(比玻璃高一个数量级)。这种透明木材制备方法高效且适用于各种木材种类。所获得的透明木材在节能建筑中显示出应用潜力。