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用于醋酸纤维素渗透透明木材的纤维素骨架的HO溶液蒸镀联合法

HO Solution Steaming Combined Method to Cellulose Skeleton for Transparent Wood Infiltrated with Cellulose Acetate.

作者信息

Zhang Jun, Ying Yongling, Yi Xiaoyang, Han Wenbo, Yin Lu, Zheng Yongjun, Zheng Rongbo

机构信息

School of Materials and Chemical Engineering, Southwest Forestry University, Kunming 650224, China.

School of Marine Science and Technology, Shanwei Institute of Technology, Shanwei 516600, China.

出版信息

Polymers (Basel). 2023 Mar 31;15(7):1733. doi: 10.3390/polym15071733.

Abstract

Hydrogen peroxide (HO) steaming, a green and highly efficient delignification method, has been demonstrated to provide a wood skeleton with a very low content of residual lignin in the manufacturing of transparent wood. It usually requires a long reaction time and a large amount of HO because the piece of wood is treated using steaming equipment. Herein, a HO solution steaming method was developed for the highly efficient removal of lignin from wood. Specifically, several wood samples were simultaneously immersed in a hot HO solution to obtain delignified wood with a relatively high content of residual lignin, which provided a high strength and preserved the cellulose skeleton. Subsequently, the delignified wood with a relatively high content of residual lignin was further treated with HO steam to obtain a very low lignin delignified wood. Compared with the previous HO steaming method, the reaction time and used HO volume of the HO solution steaming method was reduced by 37.3% and 52.7%, respectively. All-biomass transparent wood could be obtained by infiltrating the delignified wood with cellulose acetate, which showed both a high transmittance of 83.0% and a low thermal conductivity of 0.30 WmK.

摘要

过氧化氢(HO)蒸汽处理是一种绿色高效的脱木质素方法,已被证明在制造透明木材时能为木材骨架提供极低含量的残余木质素。由于使用蒸汽设备处理木材,通常需要较长的反应时间和大量的HO。在此,开发了一种HO溶液蒸汽处理方法,用于从木材中高效去除木质素。具体而言,将多个木材样品同时浸入热的HO溶液中,以获得具有较高残余木质素含量的脱木质素木材,这种木材具有较高的强度并保留了纤维素骨架。随后,对具有较高残余木质素含量的脱木质素木材进一步用HO蒸汽处理,以获得极低木质素含量的脱木质素木材。与先前的HO蒸汽处理方法相比,HO溶液蒸汽处理方法的反应时间和HO用量分别减少了37.3%和52.7%。通过用醋酸纤维素浸润脱木质素木材可得到全生物质透明木材,其具有83.0%的高透光率和0.30 WmK的低热导率。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6d9a/10097299/7817318381d0/polymers-15-01733-sch001.jpg

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