一种通过可逆加成-断裂链转移（RAFT）聚合反应和使用三唑啉二酮衍生物的超快速“点击”化学制备的可愈合热可逆功能聚合物。
A healable thermo-reversible functional polymer prepared via RAFT polymerization and ultrafast 'click' chemistry using a triazolinedione derivative.
作者信息
Mondal Prantik, Behera Prasanta Kumar, Singha Nikhil K
机构信息
Rubber Technology Centre, Indian Institute of Technology Kharagpur, Kharagpur-721302, West Bengal, India.
出版信息
Chem Commun (Camb). 2017 Aug 1;53(62):8715-8718. doi: 10.1039/c7cc02980b.
This communication reports the preparation and characterization of a functional polymer bearing a pendant indole group via a reversible-addition fragmentation and chain transfer (RAFT) process followed by its modification via an Alder-ene 'click' reaction using a 1,2,4-triazoline-3,5-dione (TAD) derivative. The resultant functional polymer showed thermo-reversible as well as healing characteristics.
本通讯报道了一种带有吲哚侧基的功能聚合物的制备与表征，该聚合物通过可逆加成-断裂链转移（RAFT）过程制备，随后使用1,2,4-三唑啉-3,5-二酮（TAD）衍生物通过Alder-ene“点击”反应对其进行改性。所得功能聚合物表现出热可逆性以及自愈特性。
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