一种新型零维配位超分子纳米铅（II）化合物的合成与表征：制备纯相纳米氧化铅的前驱体
Synthesis and characterization of a new nano lead(II) 0-D coordination supramolecular compound: A precursor to produce pure phase nano-sized lead(II) oxide.
作者信息
Fard Mohammad Jaafar Soltanian, Hayati Payam, Naraghi Hakimeh Sadat, Tabeie Sayed Abbas
机构信息
Department of Chemistry, Faculty of Chemical Science, Firoozabad Branch, Islamic Azad University, P.O. Box 74715-117, Firoozabad, Fars, Iran.
Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC and The Barcelona Institute of Science and Technology, Campus UAB, Bellaterra 08193, Barcelona, Spain; Department of Chemistry, Dashtestan Branch, Islamic Azad University, Borazjan, Iran.
出版信息
Ultrason Sonochem. 2017 Nov;39:129-136. doi: 10.1016/j.ultsonch.2017.04.023. Epub 2017 Apr 18.
Nano-structure of a new 0D Pb(II) coordination supramolecular compound, Pb(8-Quin)(1), L=8-HQuin=8-hydroxyquinolin ligand has been synthesized by use of a sonochemical process and characterized by scanning electron microscopy (SEM), X-ray powder diffraction (XRPD), Fourier transform infrared spectroscopy (FTIR) and elemental analyses. The structure of compound 1 was determined by single-crystal X-ray diffraction. The single crystal X-ray data of compound 1 implies that the Pb ions are five coordinated. Each lead atom is coordinated to nitrogen and oxygen atoms of 8-hydroxyquinolin ligand. Topological analysis shows that the compound 1 is 1,2,3,4,4M12-1net. Nanoparticles of lead(II) oxide have been prepared by calcination of lead(II) coordination polymer at 500°C that were characterized by scanning electron microscopy (SEM), X-ray powder diffraction (XRPD) and IR spectroscopy.
通过声化学方法合成了一种新型零维铅（II）配位超分子化合物Pb(8-Quin)（1），其中L = 8-HQuin = 8-羟基喹啉配体，并通过扫描电子显微镜（SEM）、X射线粉末衍射（XRPD）、傅里叶变换红外光谱（FTIR）和元素分析对其进行了表征。化合物1的结构通过单晶X射线衍射确定。化合物1的单晶X射线数据表明铅离子为五配位。每个铅原子与8-羟基喹啉配体的氮原子和氧原子配位。拓扑分析表明化合物1为1,2,3,4,4M12-1网络。通过在500°C下煅烧铅（II）配位聚合物制备了氧化铅（II）纳米颗粒，并通过扫描电子显微镜（SEM）、X射线粉末衍射（XRPD）和红外光谱对其进行了表征。
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