Fard Mohammad Jaafar Soltanian, Hayati Payam, Naraghi Hakimeh Sadat, Tabeie Sayed Abbas
Department of Chemistry, Faculty of Chemical Science, Firoozabad Branch, Islamic Azad University, P.O. Box 74715-117, Firoozabad, Fars, Iran.
Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC and The Barcelona Institute of Science and Technology, Campus UAB, Bellaterra 08193, Barcelona, Spain; Department of Chemistry, Dashtestan Branch, Islamic Azad University, Borazjan, Iran.
Ultrason Sonochem. 2017 Nov;39:129-136. doi: 10.1016/j.ultsonch.2017.04.023. Epub 2017 Apr 18.
Nano-structure of a new 0D Pb(II) coordination supramolecular compound, Pb(8-Quin)(1), L=8-HQuin=8-hydroxyquinolin ligand has been synthesized by use of a sonochemical process and characterized by scanning electron microscopy (SEM), X-ray powder diffraction (XRPD), Fourier transform infrared spectroscopy (FTIR) and elemental analyses. The structure of compound 1 was determined by single-crystal X-ray diffraction. The single crystal X-ray data of compound 1 implies that the Pb ions are five coordinated. Each lead atom is coordinated to nitrogen and oxygen atoms of 8-hydroxyquinolin ligand. Topological analysis shows that the compound 1 is 1,2,3,4,4M12-1net. Nanoparticles of lead(II) oxide have been prepared by calcination of lead(II) coordination polymer at 500°C that were characterized by scanning electron microscopy (SEM), X-ray powder diffraction (XRPD) and IR spectroscopy.
通过声化学方法合成了一种新型零维铅（II）配位超分子化合物Pb(8-Quin)（1），其中L = 8-HQuin = 8-羟基喹啉配体，并通过扫描电子显微镜（SEM）、X射线粉末衍射（XRPD）、傅里叶变换红外光谱（FTIR）和元素分析对其进行了表征。化合物1的结构通过单晶X射线衍射确定。化合物1的单晶X射线数据表明铅离子为五配位。每个铅原子与8-羟基喹啉配体的氮原子和氧原子配位。拓扑分析表明化合物1为1,2,3,4,4M12-1网络。通过在500°C下煅烧铅（II）配位聚合物制备了氧化铅（II）纳米颗粒，并通过扫描电子显微镜（SEM）、X射线粉末衍射（XRPD）和红外光谱对其进行了表征。
