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Strong intramolecular calcium-π interactions with aryl substituents--requirements and limitations.
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Dehydrogenative coupling of 4-substituted pyridines mediated by a zirconium(ii) synthon: reaction pathways and dead ends.
Chem Sci. 2018 May 16;9(23):5223-5232. doi: 10.1039/c8sc01025k. eCollection 2018 Jun 21.

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1
Sodium Salts of the Bipyridine Dianion: Polymer [(bpy) {Na (dme)} ] , Cluster [(Na O) Na (bpy) (tmeda) ], and Monomer [(bpy) {Na (pmdta)} ].
Angew Chem Int Ed Engl. 1999 Apr 1;38(7):952-955. doi: 10.1002/(SICI)1521-3773(19990401)38:7<952::AID-ANIE952>3.0.CO;2-#.
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Cu(II)-Cu(I) synergistic cooperation to lead the alkyne C-H activation.
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All the lanthanides do it and even uranium does oxidation state +2.
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Direct observation of reduction of Cu(II) to Cu(I) by terminal alkynes.
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Group 3 metal stilbene complexes: synthesis, reactivity, and electronic structure studies.
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Expanding rare-earth oxidation state chemistry to molecular complexes of holmium(II) and erbium(II).
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