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Group 3 metal stilbene complexes: synthesis, reactivity, and electronic structure studies.

作者信息

Huang Wenliang, Abukhalil Paul M, Khan Saeed I, Diaconescu Paula L

机构信息

Department of Chemistry and Biochemistry, University of California, Los Angeles, California 90095, USA.

出版信息

Chem Commun (Camb). 2014 May 25;50(40):5221-3. doi: 10.1039/c3cc47505k. Epub 2013 Dec 17.

Abstract

Group 3 metal (E)-stilbene complexes supported by a ferrocene diamide ligand were synthesized and characterized. Reactivity studies showed that they behave similar to analogous naphthalene complexes. Experimental and computational results indicated that the double bond was reduced and not a phenyl ring, in contrast to a previously reported uranium (E)-stilbene complex.

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