El Afifi E M, Shahr El-Din A M, Aglan R F, Borai E H, Abo-Aly M M
Department of Analytical Chemistry and Environmental Control, Hot Laboratories and Waste Management Center (HLWMC), Egyptian Atomic Energy Authority, Post Office Code 13759, Cairo, Egypt.
Department of Analytical Chemistry and Environmental Control, Hot Laboratories and Waste Management Center (HLWMC), Egyptian Atomic Energy Authority, Post Office Code 13759, Cairo, Egypt.
Regul Toxicol Pharmacol. 2017 Oct;89:215-223. doi: 10.1016/j.yrtph.2017.07.029. Epub 2017 Jul 29.
Egyptian monazite is a promising resource and investment attractive for production of valuable metals of industrial or nuclear interest such as rare earth elements (REEs), thorium (Th) and uranium (U). The study was focused to establish a baseline framework in viewpoint of radiation protection for the workers in production of REEs from high-grade monazite treated by sodium hydroxide (NaOH) solutions. Radiological hazard indices (cancer, gonadal and other risks) were evaluated, due to emissions (α-, β- and γ-radiations) of radium-isotopes (Ra, Ra, Ra) and lead (Pb). The values of the estimated radiological hazard indices were higher than the permissible safe limits, worldwide average and varied with those reported in other countries. It was found that more than 70% of radioactivity and radiological hazardous indices resulted from emissions of Ra, while the rest was attributed to Ra, Ra and Pb. Therefore, processing of the Egyptian monazite can cause a significant radiological impact on workers through external exposure from γ-radiations and/or internal exposure through inhalation or ingestion airborne contaminated by the radionuclides. Thus, the results recommended that protection rules could be considered to prevent the radiation hazards associated with the production of the REEs from the high grade monazite attacked by caustic method.
埃及独居石是一种很有前景的资源,对生产具有工业或核价值的金属(如稀土元素(REEs)、钍(Th)和铀(U))具有投资吸引力。该研究旨在从辐射防护的角度为用氢氧化钠(NaOH)溶液处理的高品位独居石生产稀土元素的工人建立一个基线框架。评估了由于镭同位素(Ra、Ra、Ra)和铅(Pb)的排放(α、β和γ辐射)而产生的放射危害指数(癌症、性腺和其他风险)。估计的放射危害指数值高于全球平均允许安全限值,且与其他国家报告的值有所不同。结果发现,超过70%的放射性和放射危害指数来自Ra的排放,其余则归因于Ra、Ra和Pb。因此,埃及独居石的加工可能会通过γ辐射的外部照射和/或吸入或摄入被放射性核素污染的空气而导致内部照射,从而对工人造成重大的放射影响。因此,研究结果建议应考虑制定保护规则,以防止与用苛性法处理高品位独居石生产稀土元素相关的辐射危害。