CoS 纳米晶嵌入还原氧化石墨烯的微波吸收性能。
Microwave Absorption Properties of CoS Nanocrystals Embedded into Reduced Graphene Oxide.
机构信息
State Key Laboratory of Metastable Materials Science and Technology, Yanshan University , Qinhuangdao 066004, People's Republic of China.
Hebei Key Laboratory of Microstructure Material Physics, Yanshan University , Qinhuangdao 066004, People's Republic of China.
出版信息
ACS Appl Mater Interfaces. 2017 Aug 30;9(34):28868-28875. doi: 10.1021/acsami.7b06982. Epub 2017 Aug 16.
CoS nanoparticles and CoS/reduced graphene oxide (CoS/rGO) nanohybrids were fabricated by a unique single-mode microwave-assisted hydrothermal method. The microwave absorption properties of CoS/rGO composites with different rGO proportions were investigated. Morphology analysis indicated that the CoS nanoparticles were uniformly embedded into rGO without aggregation. The complex permittivity of CoS/rGO nanohybrids could be artificially tuned with the rGO proportions. For the CoS/rGO 1:2 composite, the minimum reflection loss (RL) of -56.9 dB was achieved at 10.9 GHz for the thickness of 2.2 mm; meanwhile, the RL exceeding -10 dB were obtained in the frequency range of 9.1-13.2 GHz. Compared with other rGO-based materials, CoS/rGO composite exhibited superior microwave absorption ability at a rather thin thickness and it has great potential to be used as a high-efficiency and tunable microwave absorber.
通过独特的单模微波辅助水热法制备了 CoS 纳米粒子和 CoS/还原氧化石墨烯(CoS/rGO)纳米杂化物。研究了不同 rGO 比例的 CoS/rGO 复合材料的微波吸收性能。形貌分析表明,CoS 纳米粒子均匀嵌入 rGO 中,没有聚集。通过 rGO 比例可以人为调整 CoS/rGO 纳米杂化物的复介电常数。对于 CoS/rGO 1:2 复合材料,在厚度为 2.2mm 时,在 10.9GHz 处可达到最小反射损耗(RL)-56.9dB;同时,在 9.1-13.2GHz 的频率范围内,RL 超过-10dB。与其他基于 rGO 的材料相比,CoS/rGO 复合材料在较薄的厚度下表现出优异的微波吸收能力,具有作为高效可调谐微波吸收剂的巨大潜力。