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分级蒲公英状硫化钴空心微球:自组装与可控微波吸收性能

Hierarchical dandelion-like CoS hollow microspheres: self-assembly and controllable microwave absorption performance.

作者信息

Xu Dongwei, Zhang Feifan, Guo Huanhuan, Liu Sitong, Ma Shuaijiang, Guo Xiaoqin, Chen Ping

机构信息

School of Material Science and Engineering, Henan Key Laboratory of Aeronautical Materials and Application Technology, Zhengzhou University of Aeronautics Zhengzhou Henan 450046 China

Faculty of Engineering, Huanghe Science & Technology University Zhengzhou 450063 China.

出版信息

RSC Adv. 2023 Sep 11;13(39):27147-27157. doi: 10.1039/d3ra04890j. eCollection 2023 Sep 8.


DOI:10.1039/d3ra04890j
PMID:37701276
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10493571/
Abstract

The emerging electromagnetic radiation and interference problems have promoted the rapid development of microwave absorption materials (MAMs). However, it remains a severe challenge to construct high-performance microwave absorption materials with broadband, lightweight and corrosion resistance within low filling contents. Herein, hierarchical dandelion-like CoS hollow microspheres were reasonably constructed a solvothermal-hydrothermal etching- vulcanization process. The structure morphology, composition and electromagnetic performance of all samples have been thoroughly tested. The research results demonstrated that the structure morphology of the prepared samples with a volume ratio of 1 : 1 between ethanol and HO remained intact without serious damage. Notably, the as-obtained hierarchical dandelion-like CoS hollow microspheres (25 wt%) exhibited excellent microwave absorption capacity with a minimum reflection loss (RLmin) of -47.3 dB and the corresponding effective absorption bandwidth (EAB) of 8.4 GHz at 3.3 mm. Moreover, the broadest effective absorption bandwidth (EAB, RL < -10 dB) reached 9.0 GHz (9.0-18.0 GHz) at the matching thickness of 3.2 mm. The unparalleled multiple features including hierarchical hollow structure, tunable complex permittivity as well as the enhanced impedance matching endowed CoS great promise as high-performance microwave absorbers for solving the problem of electromagnetic pollution.

摘要

新兴的电磁辐射和干扰问题推动了微波吸收材料(MAMs)的快速发展。然而,在低填充量下构建具有宽带、轻质和耐腐蚀性能的高性能微波吸收材料仍然是一项严峻的挑战。在此,通过溶剂热-水热蚀刻-硫化过程合理构建了分级蒲公英状CoS空心微球。对所有样品的结构形态、组成和电磁性能进行了全面测试。研究结果表明,乙醇与水体积比为1:1制备的样品结构形态保持完整,未受到严重破坏。值得注意的是,所制备的分级蒲公英状CoS空心微球(25 wt%)表现出优异的微波吸收能力,在3.3 mm处最小反射损耗(RLmin)为-47.3 dB,相应的有效吸收带宽(EAB)为8.4 GHz。此外,在匹配厚度为3.2 mm时,最宽有效吸收带宽(EAB,RL < -10 dB)达到9.0 GHz(9.0-18.0 GHz)。分级空心结构、可调复介电常数以及增强的阻抗匹配等无与伦比的多重特性,使CoS作为解决电磁污染问题的高性能微波吸收剂具有巨大潜力。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8480/10493571/6b1e2c0c3fb8/d3ra04890j-f12.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8480/10493571/51da7bfe077e/d3ra04890j-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8480/10493571/b594b4e3e0a8/d3ra04890j-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8480/10493571/9c96027257cd/d3ra04890j-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8480/10493571/dc5f561d6033/d3ra04890j-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8480/10493571/4ccdffa4da29/d3ra04890j-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8480/10493571/528b2f805ade/d3ra04890j-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8480/10493571/a6ad28e0da71/d3ra04890j-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8480/10493571/d6064048b590/d3ra04890j-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8480/10493571/15b8de881c96/d3ra04890j-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8480/10493571/9645c23f89b8/d3ra04890j-f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8480/10493571/9f873529cece/d3ra04890j-f11.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8480/10493571/6b1e2c0c3fb8/d3ra04890j-f12.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8480/10493571/51da7bfe077e/d3ra04890j-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8480/10493571/b594b4e3e0a8/d3ra04890j-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8480/10493571/9c96027257cd/d3ra04890j-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8480/10493571/dc5f561d6033/d3ra04890j-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8480/10493571/4ccdffa4da29/d3ra04890j-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8480/10493571/528b2f805ade/d3ra04890j-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8480/10493571/a6ad28e0da71/d3ra04890j-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8480/10493571/d6064048b590/d3ra04890j-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8480/10493571/15b8de881c96/d3ra04890j-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8480/10493571/9645c23f89b8/d3ra04890j-f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8480/10493571/9f873529cece/d3ra04890j-f11.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8480/10493571/6b1e2c0c3fb8/d3ra04890j-f12.jpg

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本文引用的文献

[1]
Anion Exchange of Metal Particles on Carbon-Based Skeletons for Promoting Dielectric Equilibrium and High-Efficiency Electromagnetic Wave Absorption.

Small. 2023-10

[2]
Morphology engineering of defective graphene for microwave absorption.

J Colloid Interface Sci. 2023-6-15

[3]
Flexible cobalt nanoparticles/carbon nanofibers with macroporous structures toward superior electromagnetic wave absorption.

J Colloid Interface Sci. 2023-4-15

[4]
Optimal particle distribution induced interfacial polarization in hollow double-shell composites for electromagnetic waves absorption performance.

J Colloid Interface Sci. 2023-3-15

[5]
In Situ Formation of CoS Hollow Nanoboxes via Ion-Exchange for High-Performance Microwave Absorption.

Nanomaterials (Basel). 2022-8-21

[6]
Bio-inspired, bimetal ZIF-derived hollow carbon/MXene microstructure aim for superior microwave absorption.

J Colloid Interface Sci. 2022-11

[7]
Biomass-Derived Porous Carbon-Based Nanostructures for Microwave Absorption.

Nanomicro Lett. 2019-3-15

[8]
Hierarchical Bimetallic Ni-Co-P Microflowers with Ultrathin Nanosheet Arrays for Efficient Hydrogen Evolution Reaction over All pH Values.

ACS Appl Mater Interfaces. 2019-11-1

[9]
Textile-based high-performance hydrogen evolution of low-temperature atomic layer deposition of cobalt sulfide.

Nanoscale. 2019-1-17

[10]
Porous Graphene Microflowers for High-Performance Microwave Absorption.

Nanomicro Lett. 2018

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