Claverie Marie, Dumas Angela, Carême Christel, Poirier Mathilde, Le Roux Christophe, Micoud Pierre, Martin François, Aymonier Cyril
Imerys, 2 place Édouard Bouillières, 31100, Toulouse, France.
Geosciences Environment Toulouse (GET), UMR 5563, UPS-CNRS-IRD-CNES, ERT 1074 Géomatériaux, 14, Avenue Êdouard Belin, 31400, Toulouse, France.
Chemistry. 2018 Jan 12;24(3):519-542. doi: 10.1002/chem.201702763. Epub 2017 Oct 18.
This contribution gives a comprehensive review about the progress in preparation methods, properties and applications of the different synthetic talc types: i) crystalline nanotalc synthesized by hydrothermal treatment; ii) amorphous and/or short-range order nanotalc obtained by precipitation, and iii) organic-inorganic hybrid talc-like structures obtained through a sol-gel process or a chemical grafting. Several advantages of nanotalc such as high chemical purity, high surface area, tunable submicronic size, high thermal stability, and hydrophilic character (leading to be the first fluid mineral) are emphasized. Synthetic nanotalc applications are also considered including its use as nanofiller in composite materials, as absorbers of organic compounds, as anticorrosion coatings and as agents for cosmetic applications. Regarding their high industrial application potential, intensive research has been carried out to better understand their behavior and develop processes to produce them. To facilitate further research and development, scientific and technical challenges are discussed in this Review article.
本文全面综述了不同类型合成滑石在制备方法、性能及应用方面的进展:i)通过水热处理合成的结晶纳米滑石;ii)通过沉淀法获得的无定形和/或短程有序纳米滑石;iii)通过溶胶-凝胶法或化学接枝法得到的有机-无机杂化类滑石结构。文中强调了纳米滑石的几个优点,如高化学纯度、高比表面积、可调节的亚微米尺寸、高热稳定性以及亲水性(使其成为第一种流动性矿物)。还讨论了合成纳米滑石的应用,包括其作为复合材料中的纳米填料、有机化合物的吸收剂、防腐涂层以及化妆品应用的原料。鉴于其巨大的工业应用潜力,人们已开展了深入研究以更好地了解其性能并开发生产工艺。为促进进一步的研究与开发,本文讨论了相关科学技术挑战。