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基于十四醇/月桂酸/膨胀珍珠岩/铝粉的新型相变材料板用于建筑蓄热的研究

A Study on a Novel Phase Change Material Panel Based on Tetradecanol/Lauric Acid/Expanded Perlite/Aluminium Powder for Building Heat Storage.

作者信息

Wang Enyu, Kong Xiangfei, Rong Xian, Yao Chengqiang, Yang Hua, Qi Chengying

机构信息

School of Energy and Environmental Engineering, Hebei University of Technology, Tianjin 300401, China.

School of Civil Engineering, Hebei University of Technology, Tianjin 300401, China.

出版信息

Materials (Basel). 2016 Nov 5;9(11):896. doi: 10.3390/ma9110896.

Abstract

Phase change material (PCM) used in buildings can reduce the building energy consumption and indoor temperature fluctuation. A composite PCM has been fabricated by the binary eutectic mixture of tetradecanol (TD) and lauric acid (LA) absorbed into the expanded perlite (EP) using vacuum impregnation method, and its thermal conductivity was promoted by aluminium powder (AP) additive. Besides, the styrene-acrylic emulsion has been mixed with the composite PCM particles to form the protective film, so as to solve the problem of leakage. Thus, a novel PCM panel (PCMP) has been prepared using compression moulding forming method. The thermal property, microstructure characteristic, mechanical property, thermal conductivity, thermal reliability and leakage of the composite PCM have been investigated and analysed. Meanwhile, the thermal performance of the prepared PCMP was tested through PCMPs installed on the inside wall of a cell under outdoor climatic conditions. The composite PCM has a melting temperature of 24.9 °C, a freezing temperature of 25.2 °C, a melting latent heat of 78.2 J/g and a freezing latent heat of 81.3 J/g. The thermal conductivity test exposed that the thermal conductivity has been enhanced with the addition of AP and the latent heat has been decreased, but it still remains in a high level. The leakage test result has proven that liquid PCM leaking has been avoided by the surface film method. The thermal performance experiment has shown the significant function of PCMP about adjusting the indoor temperature and reducing the heats transferring between the wall inside and outside. In view of the thermal performance, mechanical property and thermal reliability results, it can be concluded that the prepared PCMP has a promising building application potential.

摘要

建筑中使用的相变材料(PCM)可以降低建筑能耗和室内温度波动。通过真空浸渍法将十四醇(TD)和月桂酸(LA)的二元共晶混合物吸收到膨胀珍珠岩(EP)中制备了一种复合PCM,并通过添加铝粉(AP)提高了其热导率。此外,将苯丙乳液与复合PCM颗粒混合形成保护膜,以解决泄漏问题。因此,采用模压成型法制备了一种新型PCM板(PCMP)。对复合PCM的热性能、微观结构特征、力学性能、热导率、热可靠性和泄漏情况进行了研究和分析。同时,通过安装在室外气候条件下的牢房内壁上的PCMP测试了所制备PCMP的热性能。复合PCM的熔化温度为24.9℃,凝固温度为25.2℃,熔化潜热为78.2J/g,凝固潜热为81.3J/g。热导率测试表明,添加AP后热导率提高,潜热降低,但仍保持在较高水平。泄漏测试结果证明,通过表面成膜法避免了液态PCM的泄漏。热性能实验表明,PCMP在调节室内温度和减少墙体内外热传递方面具有显著作用。鉴于热性能、力学性能和热可靠性结果,可以得出结论,所制备的PCMP具有良好的建筑应用潜力。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/916b/5457220/2d4f2b780efa/materials-09-00896-g001.jpg

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