（5-{3-[(1,4,7,10,13-五氧杂-16-氮杂环十八烷-16-基)羰基氨基]苯基}-10,15,20-三苯基卟啉inato）钴（II）的晶体结构
Crystal structure of (5-{3-[(1,4,7,10,13-penta-oxa-16-aza-cyclo-octa-decan-16-yl)carbonyl-amino]-phen-yl}-10,15,20-tri-phenyl-porphyrinato)cobalt(II).
作者信息
Wu Qi, He Mingrui, Li Jianfeng
机构信息
College of Material Science and Opto-electronic Technology, University of Chinese Academy of Sciences, Yanqi Lake, Huairou District, Beijing 101408, People's Republic of China.
出版信息
Acta Crystallogr E Crystallogr Commun. 2017 Jun 7;73(Pt 7):963-966. doi: 10.1107/S2056989017007745. eCollection 2017 Jul 1.
Abstract
In the title compound, [Co(CHNO)], the central Co atom is coordinated by four pyrrole N atoms of the porphyrin core and one O atom of the crown ether. The complex has a distorted porphyrin core, with mean absolute core-atom displacements of 0.14 (10) (), 0.20 (10) (), 0.24 (4) () and 0.18 (10) Å (), respectively. The axial Co-O bond length is 2.3380 (15) and the average Co-N bond length is 1.968 (5) Å. Intra-molecular N-H⋯O and inter-molecular C-H⋯π inter-actions are observed.
摘要
在标题化合物[Co(CHNO)]中，中心钴原子由卟啉核的四个吡咯氮原子和冠醚的一个氧原子配位。该配合物具有扭曲的卟啉核，平均绝对核原子位移分别为0.14 (10) ()、0.20 (10) ()、0.24 (4) ()和0.18 (10) Å ()。轴向Co-O键长为2.3380 (15)，平均Co-N键长为1.968 (5) Å。观察到分子内N-H⋯O和分子间C-H⋯π相互作用。
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本文引用的文献
1
Syn-anti conformational switching in an ethane-bridged Co(II)bisporphyrin induced by external stimuli: effects of inter-macrocyclic interactions, axial ligation and chemical and electrochemical oxidations.
Dalton Trans. 2014 Feb 7;43(5):2301-14. doi: 10.1039/c3dt52784k.
2
L-nipecotic acid-porphyrin derivative: a chiral host with introverted functionality for chiral recognition.
Org Lett. 2012 Jul 20;14(14):3652-5. doi: 10.1021/ol301499w. Epub 2012 Jul 9.
3
Conversion of cobalt(II) porphyrin into a helical cobalt(III) complex of acyclic pentapyrrole.
Angew Chem Int Ed Engl. 2011 Jul 11;50(29):6583-6. doi: 10.1002/anie.201102144. Epub 2011 Jun 6.
4
A glycyl-substituted porphyrin as a starting compound for the synthesis of a pi-pi-stacked porphyrin-fullerene dyad with a frozen geometry.
Org Biomol Chem. 2009 Mar 21;7(6):1093-6. doi: 10.1039/b820501a. Epub 2009 Feb 5.
5
A short history of SHELX.
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
6
Coordination and structural studies of crowned-porphyrins.
Dalton Trans. 2007 Sep 7(33):3684-9. doi: 10.1039/b701889d. Epub 2007 Jul 3.
7
Iron(III) complex of a crown ether-porphyrin conjugate and reversible binding of superoxide to its Iron(II) form.
J Am Chem Soc. 2007 Apr 11;129(14):4217-28. doi: 10.1021/ja064984p. Epub 2007 Mar 20.
8
Isocyanate as a Versatile Synthon for Modular Synthesis of Functionalized Porphyrins.
J Org Chem. 1998 Apr 17;63(8):2424-2425. doi: 10.1021/jo980042u.
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