A glycyl-substituted porphyrin as a starting compound for the synthesis of a pi-pi-stacked porphyrin-fullerene dyad with a frozen geometry.

作者信息

Lembo Angelo, Tagliatesta Pietro, Cicero Daniel, Leoni Alessandro, Salvatori Alisa

机构信息

Dipartimento di Scienze e Tecnologie Chimiche, University of Rome-Tor Vergata, Via della Ricerca Scientifica, 00133, Rome, Italy.

出版信息

Org Biomol Chem. 2009 Mar 21;7(6):1093-6. doi: 10.1039/b820501a. Epub 2009 Feb 5.

DOI:10.1039/b820501a

PMID:19262927

Abstract

A synthetic route for obtaining a porphyrin-fullerene dyad with a constrained geometry forcing the [60]fullerene sphere to lie on the porphyrin plane is reported, revealing a strong interaction in the ground state between the two chromophores.

摘要

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