• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

（）-2-羟基-1,2-二苯基乙酮肟的晶体结构

Crystal structure of ()-2-hy-droxy-1,2-di-phenyl-ethan-1-one oxime.

作者信息

Reuter Hans, Okio Coco K Y A

机构信息

Institute of Chemistry of New Materials, University of Osnabrück, Barbarastrasse 7, 49069 Osnabrück, Germany.

Departamento de Química, Facultad de Ciencias, Universidad Nacional de Colombia, Carerra 30 No 45-03, Bogotá, Colombia.

出版信息

Acta Crystallogr E Crystallogr Commun. 2017 Jun 20;73(Pt 7):1062-1065. doi: 10.1107/S2056989017008866. eCollection 2017 Jul 1.

DOI:10.1107/S2056989017008866
PMID:28775883
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5499291/
Abstract

The title compound, CHNO, is a commercially available material and can be used as a multidentate ligand. The mol-ecule of the asymmetric unit has an configuration, while the corresponding -configured mol-ecule of the racemic mixture is generated by a crystallographic centre of symmetry. Both hy-droxy groups (the H atom of the oxime group is equally disordered over two positions) are involved in hydrogen bonding, leading to the formation of chains extending parallel to [001].

摘要

标题化合物CHNO是一种市售材料，可用作多齿配体。不对称单元的分子具有构型，而外消旋混合物中相应构型的分子由晶体学对称中心产生。两个羟基（肟基的H原子在两个位置上同等无序）都参与氢键形成，导致形成平行于[001]延伸的链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/37fb/5499291/78619e26cc1b/e-73-01062-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/37fb/5499291/14f3e56e9e5d/e-73-01062-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/37fb/5499291/69ae365a0a78/e-73-01062-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/37fb/5499291/a6f5ed4d7ab8/e-73-01062-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/37fb/5499291/78619e26cc1b/e-73-01062-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/37fb/5499291/14f3e56e9e5d/e-73-01062-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/37fb/5499291/69ae365a0a78/e-73-01062-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/37fb/5499291/a6f5ed4d7ab8/e-73-01062-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/37fb/5499291/78619e26cc1b/e-73-01062-fig4.jpg

相似文献

1
Crystal structure of ()-2-hy-droxy-1,2-di-phenyl-ethan-1-one oxime.（）-2-羟基-1,2-二苯基乙酮肟的晶体结构
Acta Crystallogr E Crystallogr Commun. 2017 Jun 20;73(Pt 7):1062-1065. doi: 10.1107/S2056989017008866. eCollection 2017 Jul 1.
2
Synthesis and crystal structures of 5,5'-(propane-2,2-di-yl)bis-(2-hy-droxy-benzaldehyde) and 5,5'-(propane-2,2-di-yl)bis-(2-hy-droxy-isophthalaldehyde).5,5'-（丙烷-2,2-二亚基）双-（2-羟基苯甲醛）和5,5'-（丙烷-2,2-二亚基）双-（2-羟基间苯二甲醛）的合成与晶体结构
Acta Crystallogr E Crystallogr Commun. 2018 Nov 22;74(Pt 12):1872-1877. doi: 10.1107/S2056989018016316. eCollection 2018 Dec 1.
3
Crystal structure of 2-(di-phenyl-phos-phanyl)phenyl 4-(hy-droxy-meth-yl)benzoate.2-（二苯基膦基）苯基4-（羟甲基）苯甲酸酯的晶体结构
Acta Crystallogr Sect E Struct Rep Online. 2014 Nov 26;70(Pt 12):o1288-9. doi: 10.1107/S1600536814024623. eCollection 2014 Dec 1.
4
Crystal structure of 2-(2,3-di-methyl-anilino)-N'-[(1E)-2-hy-droxy-benzyl-idene]benzohydrazide.2-(2,3-二甲基苯胺基)-N'-[(1E)-2-羟基亚苄基]苯甲酰肼的晶体结构
Acta Crystallogr E Crystallogr Commun. 2015 Nov 21;71(Pt 12):o957-8. doi: 10.1107/S2056989015021532. eCollection 2015 Dec 1.
5
Crystal structures and Hirshfeld surfaces of four meth-oxy-benzaldehyde oxime derivatives, 2-MeO-CHC=NOH ( = H and 2-, 3- and 4-MeO): different conformations and hydrogen-bonding patterns.四种甲氧基苯甲醛肟衍生物2-MeO-CHC=NOH（=H以及2-、3-和4-MeO）的晶体结构和 Hirshfeld 表面：不同构象和氢键模式
Acta Crystallogr E Crystallogr Commun. 2018 Oct 9;74(Pt 11):1553-1560. doi: 10.1107/S2056989018014020. eCollection 2018 Nov 1.
6
Different classical hydrogen-bonding patterns in three salicylaldoxime derivatives, 2-HO-4-CHC=NOH ( = Me, OH and MeO).三种水杨醛肟衍生物2-HO-4-CHC=NOH（=Me、OH和MeO）中不同的经典氢键模式。
Acta Crystallogr E Crystallogr Commun. 2018 Sep 25;74(Pt 10):1480-1485. doi: 10.1107/S2056989018013361. eCollection 2018 Oct 1.
7
Crystal structure of an aryl cyclo-hexyl nona-noid, an anti-proliferative mol-ecule isolated from the spice .一种芳基环己基壬酸酯的晶体结构，该酯是从香料中分离出的一种抗增殖分子。
Acta Crystallogr E Crystallogr Commun. 2016 Sep 5;72(Pt 10):1408-1411. doi: 10.1107/S2056989016013797. eCollection 2016 Oct 1.
8
3-Hy-droxy-4-phenyl-1-(prop-2-en-1-yl)-2,3,4,5-tetra-hydro-1H-1,5-benzodiazepin-2-one.
Acta Crystallogr Sect E Struct Rep Online. 2012 Jan;68(Pt 1):o238. doi: 10.1107/S1600536811054456. Epub 2011 Dec 23.
9
Crystal structure of 4-({5-[(E)-(3,5-di-fluoro-phen-yl)diazen-yl]-2-hy-droxy-benzyl-idene}amino)-2,2,6,6-tetra-methyl-piperidin-1-ox-yl.4-({5-[(E)-(3,5-二氟苯基)重氮基]-2-羟基亚苄基}氨基)-2,2,6,6-四甲基哌啶-1-氧基的晶体结构
Acta Crystallogr E Crystallogr Commun. 2015 Jun 27;71(Pt 7):864-6. doi: 10.1107/S2056989015012049. eCollection 2015 Jul 1.
10
Crystal structure and Hirshfeld surface analysis of 2-{[2,8-bis-(tri-fluoro-meth-yl)quinolin-4-yl](hy-droxy)meth-yl}piperidin-1-ium 2-hy-droxy-2-phenyl-acetate hemihydrate.2-{[2,8-双-(三氟甲基)喹啉-4-基](羟基)甲基}哌啶-1-鎓 2-羟基-2-苯基乙酸半水合物的晶体结构和 Hirshfeld 表面分析
Acta Crystallogr E Crystallogr Commun. 2016 Oct 25;72(Pt 11):1618-1627. doi: 10.1107/S2056989016016492. eCollection 2016 Nov 1.

本文引用的文献

1
Alpha-benzoin oxime in higher oxidation state 3d metal cluster chemistry: structural and magnetic study of a new Mn(III)(9) complex.α-苯偶姻肟在高氧化态 3d 金属簇化学中的应用：新型 Mn(III)(9)配合物的结构和磁性研究。
Inorg Chem. 2010 Apr 5;49(7):3077-9. doi: 10.1021/ic100178y.
2
Initial employment of alpha-benzoin oxime as a route to high-nuclearity metal clusters: decanuclear CuII complexes with a wheel topology.
Dalton Trans. 2009 May 21(19):3646-9. doi: 10.1039/b901990a. Epub 2009 Mar 17.
3
Molecular and supramolecular Ni(II) wheels from alpha-benzoin oxime.源自α-苯偶姻肟的分子及超分子镍（II）轮状物。
Dalton Trans. 2009 May 14(18):3388-90. doi: 10.1039/b902002k. Epub 2009 Mar 20.
4
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.