通过非手性色谱法实现卤素键驱动的对映体自歧化反应（SDE）的可能案例。
Possible Case of Halogen Bond-Driven Self-Disproportionation of Enantiomers (SDE) via Achiral Chromatography.
作者信息
Terada Shumpei, Hirai Motohiro, Honzawa Ayaka, Kitagawa Osamu, Kamizela Angelika, Wzorek Alicja, Soloshonok Vadim A
机构信息
Department of Applied Chemistry, Shibaura Institute of Technology, 3-7-5 Toyosu, Kohto-ku, Tokyo, 135-8548, Japan.
Institute of Chemistry, Jan Kochanowski University in Kielce, Świętokrzyska 15G, 25-406, Kielce, Poland.
出版信息
Chemistry. 2017 Oct 17;23(58):14631-14638. doi: 10.1002/chem.201703308. Epub 2017 Sep 18.
The major breakthrough reported in this work is the discovery of likely halogen bond-driven self-disproportionation of enantiomers (SDE). Taking into account that the halogen-bonding interactions can be rationally designed and can match, or even exceed, the strength of the more familiar hydrogen bond, this discovery clearly opens an unexpected new direction of research in the areas of molecular chirality and the SDE phenomenon.
这项工作报道的主要突破是发现了可能由卤键驱动的对映体自歧化反应（SDE）。考虑到卤键相互作用可以合理设计，并且能够匹配甚至超过更为人熟知的氢键的强度，这一发现显然为分子手性和SDE现象领域开辟了一个意想不到的新研究方向。
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