手性结晶海绵用于手性客体的绝对结构测定。
Chiral Crystalline Sponges for the Absolute Structure Determination of Chiral Guests.
机构信息
Department of Applied Chemistry, School of Engineering, The University of Tokyo, and ACCEL (JST) , 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan.
出版信息
J Am Chem Soc. 2017 Aug 23;139(33):11341-11344. doi: 10.1021/jacs.7b06607. Epub 2017 Aug 15.
PMID:28783333
Abstract
Chiral crystalline sponges with preinstalled chiral references were synthesized. On the basis of the known configurations of the chiral references, the absolute structures of guest compounds absorbed in the pores of the crystalline sponges can be reliably determined without crystallization or chemical modification.
摘要
手性结晶海绵具有预安装的手性参照，可以合成。在手性参照已知构型的基础上，可以可靠地确定吸附在结晶海绵孔中的客体化合物的绝对结构，而无需结晶或化学修饰。
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