Braga Mauro S, Jaimes Ruth F V V, Borysow Walter, Gomes Osmar F, Salcedo Walter J
Laboratório de Microeletrônica, Escola Politécnica da Universidade de São Paulo, São Paulo 05508-010, Brazil.
Instituto Federal de Educação, Ciência e Tecnologia de São Paulo, Cubatão 11533-160, Brazil.
Sensors (Basel). 2017 Jul 28;17(8):1730. doi: 10.3390/s17081730.
This work deals with a portable device system applied to detect and classify different metallic ions as proposed and developed, aiming its application for hydrological monitoring systems such as rivers, lakes and groundwater. Considering the system features, a portable colorimetric system was developed by using a multispectral optoelectronic sensor. All the technology of quantification and classification of metallic ions using optoelectronic multispectral sensors was fully integrated in the embedded hardware FPGA ( Field Programmable Gate Array) technology and software based on virtual instrumentation (NI LabView). The system draws on an indicative colorimeter by using the chromogen reagent of 1-(2-pyridylazo)-2-naphthol (PAN). The results obtained with the signal processing and pattern analysis using the method of the linear discriminant analysis, allows excellent results during detection and classification of Pb(II), Cd(II), Zn(II), Cu(II), Fe(III) and Ni(II) ions, with almost the same level of performance as for those obtained from the Ultravioled and visible (UV-VIS) spectrophotometers of high spectral resolution.
本研究针对所提出并开发的用于检测和分类不同金属离子的便携式设备系统展开,旨在将其应用于河流、湖泊和地下水等水文监测系统。考虑到系统特性,利用多光谱光电传感器开发了一种便携式比色系统。使用光电多光谱传感器进行金属离子定量和分类的所有技术都完全集成在基于现场可编程门阵列(FPGA)技术的嵌入式硬件以及基于虚拟仪器(NI LabView)的软件中。该系统通过使用1-(2-吡啶偶氮)-2-萘酚(PAN)显色剂借鉴了指示比色计原理。通过使用线性判别分析方法进行信号处理和模式分析所获得的结果,在检测和分类Pb(II)、Cd(II)、Zn(II)、Cu(II)、Fe(III)和Ni(II)离子时能够取得优异的结果,其性能水平与高光谱分辨率的紫外可见(UV-VIS)分光光度计所获得的结果几乎相同。