Zou Dujian, Liu Tiejun, Du Chengcheng, Teng Jun
Shenzhen Graduate School, Harbin Institute of Technology, Shenzhen 518055, China.
Materials (Basel). 2015 Jul 24;8(8):4652-4667. doi: 10.3390/ma8084652.
Carbonation is one of the major deteriorations that accelerate steel corrosion in reinforced concrete structures. Many mathematical/numerical models of the carbonation process, primarily diffusion-reaction models, have been established to predict the carbonation depth. However, the mass transfer of carbon dioxide in porous concrete includes molecular diffusion and convection mass transfer. In particular, the convection mass transfer induced by pressure difference is called penetration mass transfer. This paper presents the influence of penetration mass transfer on the carbonation. A penetration-reaction carbonation model was constructed and validated by accelerated test results under high pressure. Then the characteristics of wind pressure on the carbonation were investigated through finite element analysis considering steady and fluctuating wind flows. The results indicate that the wind pressure on the surface of concrete buildings results in deeper carbonation depth than that just considering the diffusion of carbon dioxide. In addition, the influence of wind pressure on carbonation tends to increase significantly with carbonation depth.
碳化是加速钢筋混凝土结构中钢材腐蚀的主要劣化因素之一。为预测碳化深度,已经建立了许多碳化过程的数学/数值模型,主要是扩散-反应模型。然而,二氧化碳在多孔混凝土中的传质包括分子扩散和对流传质。特别是,由压差引起的对流传质称为渗透传质。本文介绍了渗透传质对碳化的影响。构建了一个渗透-反应碳化模型,并通过高压加速试验结果进行了验证。然后,通过考虑稳定风和脉动风的有限元分析,研究了风压对碳化的影响特性。结果表明,混凝土建筑物表面的风压导致的碳化深度比仅考虑二氧化碳扩散时更深。此外,风压对碳化的影响随着碳化深度的增加而显著增大。