Naphade Rounak, Nagane Satyawan, Bansode Umesh, Tathavadekar Mukta, Sadhanala Aditya, Ogale Satishchandra
Department of Physics and Centre for Energy Science, Indian Institute of Science Education and Research (IISER), Dr. Homi Bhabha Road, Pune, 411008, India.
National Chemical Laboratory (CSIR-NCL), Dr. Homi Bhabha Road, Pune, 411008, India.
ChemSusChem. 2017 Oct 9;10(19):3722-3739. doi: 10.1002/cssc.201701093. Epub 2017 Sep 22.
Over the past few years the organic-inorganic hybrid perovskite systems have emerged as a promising class of materials for photovoltaic and electroluminescent thin-film device applications, in view of their unique set of tunable optoelectronic properties. Importantly, these materials can be easily solution-processed at low temperatures and as such are amenable to facile molecular engineering. Thus, a variety of low-dimensional forms and quantum structures of these materials can be obtained through strategic synthetic manipulations through small molecule incorporation or molecular ion doping. In this Minireview, we specifically focus on these approaches and outline the possibilities of utilizing these for enhanced functionalities and newer application domains.
在过去几年中,有机-无机杂化钙钛矿体系已成为一类很有前景的材料,可用于光伏和电致发光薄膜器件应用,这得益于其独特的一组可调节光电特性。重要的是,这些材料可以在低温下轻松地通过溶液处理,因此适合进行简便的分子工程。因此,通过小分子掺入或分子离子掺杂等策略性合成操作,可以获得这些材料的各种低维形式和量子结构。在这篇微型综述中,我们特别关注这些方法,并概述利用它们实现增强功能和新应用领域的可能性。