Falaise Clément, Hickam Sarah M, Burns Peter C, Nyman May
Energy Frontier Research Center, Materials Science of Actinides, USA.
Chem Commun (Camb). 2017 Aug 24;53(69):9550-9553. doi: 10.1039/c7cc05357f.
The interplay between aqueous alkaline earth (Ca, Sr, Ba) polycationic speciation and uranyl-peroxide polyoxometalate self-assembly and evolution is described here using solution (Raman and X-ray scattering) and solid-state (microscopy, X-ray diffraction) characterization. Supramolecular assembly of Sr-encapsulated and decorated polyanions and polycations yields the fourth largest inorganic unit cell reported from single-crystal X-ray diffraction.
本文利用溶液（拉曼光谱和X射线散射）和固态（显微镜、X射线衍射）表征手段，描述了碱土金属（钙、锶、钡）水合多阳离子形态与过氧化铀多金属氧酸盐自组装及演化之间的相互作用。锶封装和修饰的聚阴离子与聚阳离子的超分子组装产生了单晶X射线衍射报道的第四大无机晶胞。
