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一种有效调控对硝基硫酚与对，对'-二巯基偶氮苯表面等离子体辅助偶联反应距离的新策略。

A new strategy for effective distance regulation of the surface plasmon assisted coupling reaction of p-nitrothiophenol to p,p'-dimercaptoazobenzene.

作者信息

Xia Lixin, Ma Caiqing, Wang Jing, Wu Shiwei, Liu Yu, Zhang Qian, Song Peng

机构信息

College of Chemistry, Liaoning University, Shenyang 110036, China.

出版信息

Chem Commun (Camb). 2017 Aug 24;53(69):9582-9585. doi: 10.1039/c7cc04780k.

DOI:10.1039/c7cc04780k
PMID:28808719
Abstract

Plasmon assisted reactions on a metal surface occur through a different mechanism compared to traditional reaction conditions. Based on a SERS study of the model plasmon assisted reaction of PNTP to DMAB, we present the first regulation strategy for these reactions, enabled here, through the controlled adjustment of acidic properties.

摘要

与传统反应条件相比，金属表面的等离子体辅助反应通过不同的机制发生。基于对PNTP与DMAB的模型等离子体辅助反应的表面增强拉曼光谱（SERS）研究，我们首次提出了针对这些反应的调控策略，此策略通过对酸性性质的可控调节得以实现。

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A new strategy for effective distance regulation of the surface plasmon assisted coupling reaction of p-nitrothiophenol to p,p'-dimercaptoazobenzene.一种有效调控对硝基硫酚与对，对'-二巯基偶氮苯表面等离子体辅助偶联反应距离的新策略。
Chem Commun (Camb). 2017 Aug 24;53(69):9582-9585. doi: 10.1039/c7cc04780k.
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Novel Clarification of Surface Plasmon Coupling Reactions of Aromatic Alkynamine and Nitro Compounds.
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