Department of Systems Innovation, School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo, 113-8656, Japan.
Chem Asian J. 2017 Oct 5;12(19):2544-2548. doi: 10.1002/asia.201701067. Epub 2017 Sep 5.
Molybdenum-catalyzed conversion of molecular dinitrogen into ammonia under ambient reaction conditions has been achieved by using a proton source generated in situ from the ruthenium-catalyzed oxidation of water in combination with visible light and a photosensitizer. The preset reaction system is considered as a new model for the nitrogen fixation by photosynthetic bacteria.
钼催化体系在质子源（原位生成，由钌催化氧化水产生）、可见光和光敏剂的共同作用下，于温和条件下实现了氮气到氨的转化。该预设反应体系被认为是模拟光合细菌固氮作用的新模式。
