Department of Chemistry, School of Pharmaceutical and Chemical Engineering, Taizhou University, 1139 Shifu Road, Taizhou, 318000, Zhejiang Province, People's Republic of China.
Department of Chemistry, Institute of Molecular Functional Materials, Hong Kong Baptist University, Waterloo Road, Hong Kong, People's Republic of China.
Top Curr Chem (Cham). 2017 Aug 17;375(5):77. doi: 10.1007/s41061-017-0164-1.
This review focuses on the recent development in the rigid-rod metallopolymers of late transition metals based on triple-bond building blocks. The synthesis, structure-property relationships and potential applications of organometallic poly(arylene ethynylene)s will be discussed in detail. These functional metal-based polymers can exhibit intriguing optical, electronic and magnetic properties. Considerable focus is placed on the design strategies towards tuning the optical bandgap and emission color (spanning almost the whole visible spectrum) of this class of metallopolymers, and the investigation of their use as active materials for light/electrical energy conversion and energy and information storage. The ongoing scientific challenges and future prospects of this research field are also highlighted.
这篇综述重点介绍了基于三键构建块的后过渡金属刚性棒状金属聚合物的最新进展。详细讨论了有机金属聚（亚芳基乙炔）的合成、结构-性能关系和潜在应用。这些功能金属基聚合物可以表现出有趣的光学、电子和磁性性质。相当大的重点放在了设计策略上，以调整这一类金属聚合物的光学带隙和发射颜色（几乎涵盖整个可见光谱），并研究它们作为用于光/电能转换以及能量和信息存储的活性材料的用途。还强调了该研究领域当前的科学挑战和未来前景。
