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双（乙酸根-κO）[4'-（4-（二苯胺基）苯基）]（2,2':6',2''-三联吡啶-κN,N',N''）锌（II）及其聚合物中的机械变色、热变色、溶剂变色和气相变色现象

Mechano-, thermo-, solvato-, and vapochromism in bis(acetato-κO)[4'-(4-(diphenylamino)phenyl)](2,2':6',2''-terpyridine-κN,N',N'')zinc(ii) and its polymer.

作者信息

Tsukamoto Takamasa, Aoki Risa, Sakamoto Ryota, Toyoda Ryojun, Shimada Masaki, Hattori Yohei, Kitagawa Yasutaka, Nishibori Eiji, Nakano Masayoshi, Nishihara Hiroshi

机构信息

Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.

出版信息

Chem Commun (Camb). 2017 Aug 29;53(70):9805-9808. doi: 10.1039/c7cc05022d.

DOI:10.1039/c7cc05022d
PMID:28820190
Abstract

The titled complex exhibits multi-functional luminochromism in the solid state, despite its simple chemical structure. The complex shows solid-state vapochromism and mechanochromism. The polymer analogue of the complex undergoes solvatochromism and thermochromism.

摘要

尽管该标题配合物的化学结构简单，但它在固态下表现出多功能发光变色现象。该配合物呈现固态气致变色和机械变色现象。该配合物的聚合物类似物会发生溶剂致变色和热致变色现象。

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