syn-BN-heteroacene cored conjugated oligomers with finely tuned blue-violet luminescent properties.
作者信息
Zhang Wanzheng, Fu Yubin, Qiang Peirong, Hunger Jens, Bi Shuai, Zhang Wenbei, Zhang Fan
机构信息
School of Chemistry and Chemical Engineering, State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, P. R. China.
出版信息
Org Biomol Chem. 2017 Aug 30;15(34):7106-7111. doi: 10.1039/c7ob01679d.
PMID:28820537
Abstract
Initiated by the effective dibromination of syn-BN-heteroacenes, a series of BN-containing conjugated oligomers was successfully synthesized upon transition-metal-catalyzed cross coupling. Their electronic structures can be finely tailored through varying the fused backbone or terminal substituents, endowing them with tunable luminescent properties within blue-violet regions.
摘要
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