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含氮氨基酸化合物功能化氧化石墨烯:合成、表征及其在废水污染物去除中的应用:综述。

Nitrogen-containing amino compounds functionalized graphene oxide: Synthesis, characterization and application for the removal of pollutants from wastewater: A review.

机构信息

College of Environmental Science and Engineering, Hunan University, Changsha 410082, PR China; Key Laboratory of Environmental Biology and Pollution Control (Hunan University), Ministry of Education, Changsha 410082, PR China.

College of Environmental Science and Engineering, Hunan University, Changsha 410082, PR China; Key Laboratory of Environmental Biology and Pollution Control (Hunan University), Ministry of Education, Changsha 410082, PR China.

出版信息

J Hazard Mater. 2018 Jan 15;342:177-191. doi: 10.1016/j.jhazmat.2017.06.071. Epub 2017 Jul 3.

Abstract

Nowadays, using graphene oxide (GO) as an adsorbent for removing pollutants from wastewater has attracted increasing attention due to its unique physic-chemical properties. Nitrogen-containing amino (NA) compounds have excellently complexing properties due to their abundant amino functional groups. In order to obtain an innovative adsorbent, functionalized GO (NAGO) has been developed by combining the properties of GO with the advantages of NA compounds. The obtained NAGO composites usually exhibit great improvement in adsorption properties and can be used as a promising adsorbent for decontamination of wastewater. This paper reviewed recent progress of synthetic technologies about fabricating various NAGOs, and their morphologies, structures and functional characteristics. Meanwhile, important applications of NAGOs for different kind of pollutants and theory of the adsorption phenomena are discussed based on the isothermal and kinetic adsorption models. Furthermore, the affecting factors, underlying mechanisms and comparison with other adsorbents for the removal of pollutants are reviewed. Conclusively, the perspectives and challenges involved in the application of NAGOs for decontamination of wastewater have also been proposed to promote sustainable development of this new exciting field.

摘要

如今,由于其独特的物理化学性质,氧化石墨烯(GO)作为一种吸附剂来去除废水中的污染物引起了越来越多的关注。含氮氨基酸(NA)化合物由于其丰富的氨基官能团而具有极好的络合性能。为了获得一种创新的吸附剂,通过将 GO 的性质与 NA 化合物的优势相结合,开发了功能化 GO(NAGO)。所得的 NAGO 复合材料通常在吸附性能方面表现出很大的改善,可以用作废水净化的有前途的吸附剂。本文综述了近年来制备各种 NAGOs 的合成技术的最新进展,以及它们的形态、结构和功能特性。同时,根据等温吸附和动力学吸附模型,讨论了 NAGOs 对不同类型污染物的重要应用和吸附现象的理论。此外,还综述了去除污染物的影响因素、潜在机制以及与其他吸附剂的比较。最后,还提出了 NAGOs 在废水净化中的应用所涉及的观点和挑战,以促进这一令人兴奋的新领域的可持续发展。

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