无金属氧化还原活性低共熔溶剂
Metal-free redox active deep eutectic solvents.
作者信息
Goeltz J C, Matsushima L N
机构信息
California State University, Monterey Bay, School of Natural Sciences, 100 Campus Center, Seaside, CA 93955, USA.
出版信息
Chem Commun (Camb). 2017 Sep 16;53(72):9983-9985. doi: 10.1039/c7cc04837h. Epub 2017 Aug 23.
PMID:28831464
Abstract
Metal-free deep eutectic solvents composed of hydrogen bond donors and viologen-based ammonium salts exhibit reversible electrochemistry with viologen concentrations of 4.2 M and freezing points near room temperature. Spectroelectrochemistry and simulation of voltammetry indicate poor aggregation of the reduced radical cation.
摘要
由氢键供体和基于紫精的铵盐组成的无金属深共熔溶剂，在紫精浓度为4.2 M且冰点接近室温的情况下表现出可逆电化学性质。光谱电化学和伏安法模拟表明还原自由基阳离子的聚集程度较低。
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