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基于碘铅酸盐和紫精配位聚合物的供体-受体杂化异质结构的组装

Assembly of donor-acceptor hybrid heterostructures based on iodoplumbates and viologen coordination polymers.

作者信息

Liu Jian-Jun, Shan Yue-Bin, Dai Wen-Xin, Huang Chang-Cang, Lin Mei-Jin

机构信息

State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, 350116, China.

出版信息

Dalton Trans. 2017 Sep 12;46(35):11556-11560. doi: 10.1039/c7dt02133j.

DOI:10.1039/c7dt02133j
PMID:28836640
Abstract

The insertion of electron-rich iodoplumbate nanowires and nanolayers into layered electron-deficient metal-viologen frameworks leads to two donor-acceptor hybrid structures, respectively, which exhibit interesting semiconductor behaviors. Due to the bicontinuous donor and acceptor components, both of them exhibit highly efficient photocatalytic degradation activities over organic dyes under visible light irradiation compared to those of other iodoplumbate hybrid materials.

摘要

将富电子的碘铅酸盐纳米线和纳米层插入层状缺电子金属紫精骨架中,分别形成两种供体-受体杂化结构,它们表现出有趣的半导体行为。由于供体和受体组分的双连续结构,与其他碘铅酸盐杂化材料相比,它们在可见光照射下对有机染料均表现出高效的光催化降解活性。

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