Li Xiao-Xin, Shen Feng-Cui, Liu Jiang, Li Shun-Li, Dong Long-Zhang, Fu Qiang, Su Zhong-Min, Lan Ya-Qian
Institute of Functional Material Chemistry, Department of Chemistry, National & Local United Engineering Lab for Power Battery, Northeast Normal University, Changchun 130024, Jilin, P. R. China.
Chem Commun (Camb). 2017 Sep 5;53(72):10054-10057. doi: 10.1039/c7cc05552h.
A novel polyoxometalate-based metal-organic framework (POMOF) with an ABW network, NENU-601, was synthesized in situ. To the best of our knowledge, this is the first POMOF with a zeolite-like structure, which was designed by regulating the length and angle of mixed ligands and rationally choosing suitable Polyoxometalates (POMs) as nodes.
原位合成了一种具有ABW网络结构的新型基于多金属氧酸盐的金属有机框架（POMOF），即NENU-601。据我们所知，这是首个具有类沸石结构的POMOF，它是通过调节混合配体的长度和角度并合理选择合适的多金属氧酸盐（POMs）作为节点来设计的。
