Ma Ben, Wu Jiaojiao, Liu Lu, Zhang Junliang
Shanghai Key Laboratory of Green Chemistry and Chemical Process, School of Chemistry and Molecular Engineering, East China Normal University, 3663 N. Zhongshan Road, Shanghai 200062, China.
Chem Commun (Camb). 2017 Sep 12;53(73):10164-10167. doi: 10.1039/c7cc05649d.
Herein, we report a gold-catalyzed highly site-selective C(sp)-H functionalization of unactivated arenes with α-aryl-α-diazoesters with electron-withdrawing substituents as induced groups on aryl rings. Furthermore, the induced groups are useful for further synthetic transformations.
在此，我们报道了一种金催化的未活化芳烃与α-芳基-α-重氮酯的高度位点选择性C(sp)-H官能团化反应，其中芳基环上带有吸电子取代基作为诱导基团。此外，这些诱导基团可用于进一步的合成转化。
