金催化苯衍生物与供体/受体取代的重氮化合物的对位选择性C-H键烷基化反应。
Gold-catalyzed para-selective C-H bond alkylation of benzene derivatives with donor/acceptor-substituted diazo compounds.
作者信息
Ma Ben, Wu Jiaojiao, Liu Lu, Zhang Junliang
机构信息
Shanghai Key Laboratory of Green Chemistry and Chemical Process, School of Chemistry and Molecular Engineering, East China Normal University, 3663 N. Zhongshan Road, Shanghai 200062, China.
出版信息
Chem Commun (Camb). 2017 Sep 12;53(73):10164-10167. doi: 10.1039/c7cc05649d.
PMID:28850128
Abstract
Herein, we report a gold-catalyzed highly site-selective C(sp)-H functionalization of unactivated arenes with α-aryl-α-diazoesters with electron-withdrawing substituents as induced groups on aryl rings. Furthermore, the induced groups are useful for further synthetic transformations.
摘要
在此，我们报道了一种金催化的未活化芳烃与α-芳基-α-重氮酯的高度位点选择性C(sp)-H官能团化反应，其中芳基环上带有吸电子取代基作为诱导基团。此外，这些诱导基团可用于进一步的合成转化。
Zotero 插件