Dornsiepen Eike, Eußner Jens P, Rosemann Nils W, Chatterjee Sangam, Dehnen Stefanie
Fachbereich Chemie and Wissenschaftliches Zentrum für Materialwissenschaften, Philipps-Universität Marburg , Hans-Meerwein-Straße, 35043 Marburg, Germany.
Institute of Experimental Physics I, Justus-Liebig-University Gießen , Heinrich-Buff-Ring 16, D-35392 Gießen, Germany.
Inorg Chem. 2017 Sep 18;56(18):11326-11335. doi: 10.1021/acs.inorgchem.7b01713. Epub 2017 Sep 1.
We report that reactions of the binary organotin sulfide cluster [(RSn)S]Cl [A; R = CMeCHC(O)Me] with gold(I) phosphane complexes yield discrete ternary complexes [(RSn)(AuPMe)S] (1) and [(RSn)(AuPMe)S] [2; R = CMeCHC(NNH)Me], which are related to recently published complexes [(RSn)(AuPPh)S] (B and C). Further, we present a binary tin sulfide cluster that cocrystallizes with a structure-directing salt of a gold phosphane complex in [Au(dppe)][(RSn)SCl] [3; R = CMeCHC(NNHPh)Me]. The nature of the product depends on the choice of the phosphane ligand as well as the addition of hydrazine hydrate or phenylhydrazine. Additionally, we report on the photophysical properties of 1, 2, B, and C, which indicate that the different phosphane ligands only have a slight influence on the optical responses. The structure, however, has a significant impact on the luminescence efficiency.
我们报道，二元有机锡硫化物簇[(RSn)S]Cl [A；R = CMeCHC(O)Me]与金(I)膦配合物的反应生成离散的三元配合物[(RSn)(AuPMe)S] (1)和[(RSn)(AuPMe)S] [2；R = CMeCHC(NNH)Me]，它们与最近发表的配合物[(RSn)(AuPPh)S] (B和C)相关。此外，我们展示了一种二元硫化锡簇，它与金膦配合物的结构导向盐在[Au(dppe)][(RSn)SCl] [3；R = CMeCHC(NNHPh)Me]中形成共晶体。产物的性质取决于膦配体的选择以及水合肼或苯肼的添加。此外，我们报道了1、2、B和C的光物理性质，这表明不同的膦配体对光学响应只有轻微影响。然而，结构对发光效率有显著影响。
