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基于{Fe₆O₂}的十四核铁纳米簇组装体。

{Fe₆O₂}-Based Assembly of a Tetradecanuclear Iron Nanocluster.

作者信息

Baca Svetlana G, Speldrich Manfred, Ellern Arkady, Kögerler Paul

机构信息

Institute of Inorganic Chemistry, RWTH Aachen University, 52074 Aachen, Germany.

Institute of Chemistry, Academy of Sciences of Moldova, MD2028 Chisinau, Moldova.

出版信息

Materials (Basel). 2011 Jan 19;4(1):300-310. doi: 10.3390/ma4010300.

DOI:10.3390/ma4010300
PMID:28879990
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5448473/
Abstract

The tetradecanuclear Fe pivalate nanocluster [FeO(OH)₄(Piv)], comprising a new type of metal oxide framework, has been solvothermally synthesized from a hexanuclear iron pivalate precursor in dichlormethane/acetonitrile solution. Magnetic measurements indicate the presence of very strong antiferromagnetic interactions in the cluster core.

摘要

十四核新戊酸铁纳米簇[FeO(OH)₄(Piv)]由一种新型金属氧化物骨架构成，它是在二氯甲烷/乙腈溶液中通过溶剂热法从六核新戊酸铁前驱体合成得到的。磁性测量表明该簇核中存在非常强的反铁磁相互作用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dafe/5448473/cc37df1403ff/materials-04-00300-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dafe/5448473/b8d95a04a89b/materials-04-00300-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dafe/5448473/d2eff08a870e/materials-04-00300-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dafe/5448473/0264acb08427/materials-04-00300-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dafe/5448473/2aae034a7ec3/materials-04-00300-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dafe/5448473/cc37df1403ff/materials-04-00300-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dafe/5448473/b8d95a04a89b/materials-04-00300-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dafe/5448473/d2eff08a870e/materials-04-00300-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dafe/5448473/0264acb08427/materials-04-00300-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dafe/5448473/2aae034a7ec3/materials-04-00300-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dafe/5448473/cc37df1403ff/materials-04-00300-g004.jpg

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