Ding Jiaming, Chen Jiafu, Mao Weipeng, Huang Junrou, Ma Da
Department of Chemistry, Fudan University, 220 Handan Road, Shanghai 200433, China.
Org Biomol Chem. 2017 Sep 26;15(37):7894-7897. doi: 10.1039/c7ob02013a.
The conventional method to synthesize non-symmetric pillar[n]arenes (PA[n]s) generally results in a low yield and requires laborious isolation. We developed a new synthetic method to prepare non-symmetric PA[5]s with various substitutions. Monomers were synthesized starting from commercially available chemicals. The desired products could be easily isolated with an improved yield.
合成非对称柱[n]芳烃（PA[n]s）的传统方法通常产率较低，且需要繁琐的分离过程。我们开发了一种新的合成方法来制备具有各种取代基的非对称PA[5]s。单体由市售化学品合成。所需产物能够以更高的产率轻松分离出来。
