Grupo de Óptica, Departamento de Física Aplicada, Universidad de Cantabria, Facultad de Ciencias, Avda. Los Castros s/n, 39005, Santander, Spain.
Departamento de I+D, Textil Santanderina, S.A., Avenida Textil Santanderina, s/n, 39500, Cabezón de la Sal, Spain.
Sci Rep. 2017 Sep 11;7(1):11189. doi: 10.1038/s41598-017-11401-y.
High Refractive Index (HRI) dielectric nanoparticles have been proposed as an alternative to metallic ones due to their low absorption and magnetodielectric response in the VIS and NIR ranges. For the latter, important scattering directionality effects can be obtained. Also, systems constituted by dimers of HRI dielectric nanoparticles have shown to produce switching effects by playing with the polarization, frequency or intensity of the incident radiation. Here, we show that scattering directionality effects can be achieved with a single eccentric metallo-HRI dielectric core-shell nanoparticle. As an example, the effect of the metallic core displacements for a single Ag-Si core-shell nanoparticle has been analyzed. We report rotation of the main scattering lobe either clockwise or counterclockwise depending on the polarization of the incident radiation leading to new scattering configurations for switching purposes. Also, the efficiency of the scattering directionality can be enhanced. Finally, chains of these scattering units have shown good radiation guiding effects, and for 1D periodic arrays, redirection of diffracted intensity can be observed as a consequence of blazing effects. The proposed scattering units constitute new blocks for building systems for optical communications, solar energy harvesting devices and light guiding at the nanoscale level.
高折射率 (HRI) 介电纳米粒子由于其在可见光和近红外范围内的低吸收和磁电响应而被提议作为金属纳米粒子的替代品。对于后者,可以获得重要的散射各向异性效应。此外,由 HRI 介电纳米粒子的二聚体构成的系统通过调节入射辐射的极化、频率或强度已经显示出产生开关效应的能力。在这里,我们展示了可以通过单个偏心金属-HRI 介电核壳纳米粒子来实现散射各向异性效应。例如,已经分析了单个 Ag-Si 核壳纳米粒子的金属核位移对散射方向的影响。我们报告了主要散射瓣的顺时针或逆时针旋转,这取决于入射辐射的偏振,从而导致新的散射配置以实现开关目的。此外,可以增强散射各向异性的效率。最后,这些散射单元的链已经显示出良好的辐射引导效果,并且对于 1D 周期性阵列,可以观察到由于闪耀效应而导致的衍射强度的重新定向。所提出的散射单元构成了用于光通信、太阳能收集器件和纳米级光导的系统构建的新模块。