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活性污泥系统对砷的去除及迁移转化机制研究

Study on the removal and transport and migration mechanism for As with activated sludge system.

作者信息

Zhang Jin, Wei Wei, Lin Shuang, Lu Jie, Hu Qing

机构信息

School of Environmental Science and Engineering, Dalian Maritime University, Dalian, 116026, People's Republic of China.

出版信息

AMB Express. 2017 Sep 13;7(1):172. doi: 10.1186/s13568-017-0478-y.

Abstract

In this paper, the removal of As and the transport and migration of As at the process of activated sludge system was studied. The results showed that the activated sludge system has high removal efficiency for As, and the removal efficiency could be nearly 100%. The initial concentration of As has effect on the removal efficiency, and within the experimental scope, the increase of initial concentration of As improved the removal efficiency for As. The distribution of As in the surface and internal in activated sludge indicates that in the process of activated sludge, the As was first transferred from water to the surface of solid and was adsorbed by the surface and then transport to the interior of microbes and take part in some metabolisms of the microorganisms. The adsorption of As by activated sludge conforms to Freundlich adsorption isotherm, and the removal of As in activated sludge system follows to the pseudo second order reaction kinetics.

摘要

本文研究了活性污泥系统中砷的去除以及砷在该过程中的迁移转化。结果表明,活性污泥系统对砷具有较高的去除效率,去除率可达近100%。砷的初始浓度对去除效率有影响,在实验范围内,砷初始浓度的增加提高了砷的去除效率。活性污泥表面和内部砷的分布表明,在活性污泥过程中,砷首先从水体转移到固体表面并被表面吸附,然后运输到微生物内部并参与微生物的一些代谢过程。活性污泥对砷的吸附符合Freundlich吸附等温线,活性污泥系统中砷的去除遵循准二级反应动力学。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2113/5597562/bfdbe6890b4e/13568_2017_478_Fig1_HTML.jpg

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