The role of metal oxide interactions: revisiting Pt growth on the TiO surface in the process of impregnation method.

First-principles calculations and experiments with PtO on TiO surfaces were performed together to understand the interactions of metal oxides during the calcination process and their influence on the growth pattern of Pt on the TiO surface. Our calculations indicate that PtO with a high concentration of oxygen binds more strongly to rutile than to anatase, indicating the formation of stronger interactions between Pt oxide and the rutile surface compared with anatase during the calcination stage under an oxidative atmosphere. X-ray photoelectron spectra quantification analysis illustrates that higher amounts of Pt oxide are obtained when impregnation is performed with a rutile support after calcination in comparison with that of anatase. After reduction, the stronger interaction between PtO and rutile leads to a larger amount of partially charged and highly dispersed Pt nanoclusters on the surface, while the weaker interaction between PtO and anatase illustrates the dispersion and sintering of higher amounts of metal nanoparticles on the anatase surface. Furthermore, the photocatalytic oxygen evolution test highlights the importance of understanding the interaction between the metal oxide and anatase/rutile for targeted synthesis of the supported catalyst.