Luxembourg Institute of Science and Technology (LIST), 5, Avenue des Hauts-Fourneaux, L-4362, Esch-sur-Alzette, Luxembourg.
Université de Toulouse, INSA,UPS,INP, LISBP, 135 Avenue de Rangueil, F-31077, Toulouse, France; INRA, UMR792 Ingénierie des Systèmes Biologiques et des Procédés, F-31400, Toulouse, France; CNRS, UMR5504, F-31400, Toulouse, France.
Water Res. 2017 Dec 1;126:50-59. doi: 10.1016/j.watres.2017.09.016. Epub 2017 Sep 8.
Innovative treatment technologies and management methods are necessary to valorise the constituents of wastewater, in particular nutrients from urine (highly concentrated and can have significant impacts related to artificial fertilizer production). The FP7 project, ValuefromUrine, proposed a new two-step process (called VFU) based on struvite precipitation and microbial electrolysis cell (MEC) to recover ammonia, which is further transformed into ammonium sulphate. The environmental and economic impacts of its prospective implementation in the Netherlands were evaluated based on life cycle assessment (LCA) methodology and operational costs. In order to tackle the lack of stable data from the pilot plant and the complex effects on wastewater treatment plant (WWTP), process simulation was coupled with LCA and costs assessment using the Python programming language. Additionally, particular attention was given to the propagation and analysis of inputs uncertainties. Five scenarios of VFU implementation were compared to the conventional treatment of 1 m of wastewater. Inventory data were obtained from SUMO software for the WWTP operation. LCA was based on Brightway2 software (using ecoinvent database and ReCiPe method). The results, based on 500 iterations sampled from inputs distributions (foreground parameters, ecoinvent background data and market prices), showed a significant advantage of VFU technology, both at a small and decentralized scale and at a large and centralized scale (95% confidence intervals not including zero values). The benefits mainly concern the production of fertilizers, the decreased efforts at the WWTP, the water savings from toilets flushing, as well as the lower infrastructure volumes if the WWTP is redesigned (in case of significant reduction of nutrients load in wastewater). The modelling approach, which could be applied to other case studies, improves the representativeness and the interpretation of results (e.g. complex relationships, global sensitivity analysis) but requires additional efforts (computing and engineering knowledge, longer calculation time). Finally, the sustainability assessment should be refined in the future with the development of the technology at larger scale to update these preliminary conclusions before its commercialization.
需要创新的治疗技术和管理方法来实现废水成分的增值,特别是尿液中的营养物质(浓度高,与人工肥料生产相关的影响显著)。FP7 项目 ValuefromUrine 提出了一种新的两步法(称为 VFU),基于鸟粪石沉淀和微生物电解池(MEC)回收氨,进一步转化为硫酸铵。根据生命周期评估(LCA)方法和运营成本,评估了其在荷兰预期实施的环境和经济影响。为了解决中试工厂缺乏稳定数据和对废水处理厂(WWTP)的复杂影响的问题,使用 Python 编程语言将过程模拟与 LCA 和成本评估相结合。此外,特别关注输入不确定性的传播和分析。将 VFU 实施的五个方案与 1 立方米废水的常规处理进行了比较。库存数据由 SUMO 软件获得,用于 WWTP 运行。LCA 基于 Brightway2 软件(使用 ecoinvent 数据库和 ReCiPe 方法)。基于从输入分布中(前景参数、ecoinvent 背景数据和市场价格)采样 500 次迭代的结果表明,VFU 技术具有显著优势,无论是在小型和分散规模上,还是在大型和集中规模上(95%置信区间不包括零值)。好处主要涉及肥料的生产、WWTP 的工作量减少、厕所冲洗的用水量节省,以及 WWTP 重新设计时基础设施体积的减少(如果废水中的营养物质负荷显著减少)。这种建模方法可以应用于其他案例研究,提高了代表性和结果的解释(例如,复杂关系,全局灵敏度分析),但需要额外的努力(计算和工程知识,更长的计算时间)。最后,随着技术在更大规模上的发展,未来应该对可持续性评估进行改进,以便在商业化之前更新这些初步结论。