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研究镧浸渍纤维素,来源于生物质,作为一种吸附剂去除饮用水中的氟化物。

Investigation of lanthanum impregnated cellulose, derived from biomass, as an adsorbent for the removal of fluoride from drinking water.

机构信息

Biomaterials in Medicinal Chemistry Laboratory, Department of Natural Products Chemistry, School of Chemistry, Madurai Kamaraj University, Madurai, Tamil Nadu 625 021, India.

Department of Mechanical & Industrial Engineering, College of Engineering, Qatar University, P.O. Box 2713, Doha, Qatar.

出版信息

Carbohydr Polym. 2017 Nov 15;176:402-410. doi: 10.1016/j.carbpol.2017.08.089. Epub 2017 Aug 24.

Abstract

High concentrations of fluoride in drinking water can cause the disease fluorosis. Our scope goal is to develop an effective biopolymeric adsorbent for the removal of fluoride to below a specific safety limit set by the World Health Organization. In this study, the natural adsorbent material cellulose was impregnated with lanthanum chloride and effectiveness in adsorbing fluoride was confirmed by FT-IR, XRD, and SEM coupled with EDX techniques. The adsorption data were analyzed by Freundlich, Langmuir, and Redlich-Peterson isotherms. The adsorption on cellulose and Lanthanum impregnated Cellulose (LaC) obeyed the pseudo second order kinetic model and thermodynamic parameters were shows the adsorption process was spontaneous and feasible. The high adsorption capacity of LaC was developed from waste materials through an easy procedure, has potential for application to efficient defluoridation. In future, the potential LaC adsorbent will be used for designing of household defluoridation unit for effective and economical fluoride removal.

摘要

高浓度的氟化物会导致氟中毒。我们的目标是开发一种有效的生物聚合吸附剂,将氟化物去除到世界卫生组织规定的特定安全限值以下。在这项研究中,天然吸附材料纤维素用氯化镧浸渍,并通过傅里叶变换红外光谱(FT-IR)、X 射线衍射(XRD)和扫描电子显微镜(SEM)结合能谱(EDX)技术证实了其对氟化物的吸附效果。吸附数据通过弗伦德利希(Freundlich)、朗缪尔(Langmuir)和雷德里希-彼得森(Redlich-Peterson)等温线进行分析。纤维素和镧浸渍纤维素(LaC)的吸附都遵循准二级动力学模型,热力学参数表明吸附过程是自发和可行的。LaC 具有较高的吸附能力,是通过简单的方法从废物中开发出来的,具有应用于高效除氟的潜力。在未来,潜在的 LaC 吸附剂将用于设计家用除氟装置,以有效和经济地去除氟化物。

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