高氯酸三（μ-甲醇根）-μ-氧代-三-{[（）-4-氯-2-{[2-（吡啶-2-基）乙基]亚氨基}-甲基]苯酚根合锰（III）}-二氯甲烷-二乙醚（1/1.1/0.9）
Tris(μ-methano-lato)-μ-oxido-tris-{[()-4-chloro-2-({[2-(pyridin-2-yl)eth-yl]imino}-meth-yl)pheno-lato]manganese(III)} perchlorate-di-chloro-methane-diethyl ether (1/1.1/0.9).
作者信息
Egekenze Rita, Gultneh Yilma, Butcher Ray J
机构信息
Department of Chemistry, Howard University, 525 College Street NW, Washington, DC 20059, USA.
出版信息
Acta Crystallogr E Crystallogr Commun. 2017 Jul 4;73(Pt 8):1113-1116. doi: 10.1107/S2056989017008982. eCollection 2017 Jul 1.
In the title compound, [Mn(CHClNO)(CHO)O]ClO·1.1CHCl·0.9CHO, the cation consists of a central MnO core with μ-methano-late bridging between adjacent Mn atoms, thus giving each Mn atom a -O coordination environment. Six-coordination for each Mn atom is provided by the deprotonated Schiff base ligand ()-4-chloro-2-({[2-(pyridin-2-yl)eth-yl]imino}-meth-yl)phenolate. There are extensive C-H⋯O and C-H⋯Cl inter-actions, which link the cations, anions, and solvent mol-ecules into a three-dimensional array.
在标题化合物[Mn(CHClNO)(CHO)O]ClO·1.1CHCl·0.9CHO中，阳离子由一个中心MnO核组成，μ-甲酸盐在相邻的Mn原子之间桥连，从而使每个Mn原子具有-O配位环境。每个Mn原子的六配位由去质子化的席夫碱配体（）-4-氯-2-（{[2-（吡啶-2-基）乙基]亚氨基}-甲基）苯酚盐提供。存在广泛的C-H⋯O和C-H⋯Cl相互作用，这些相互作用将阳离子、阴离子和溶剂分子连接成三维阵列。
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