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Crystal structure and DFT study of bis-{()-2-[(2-hy-droxy-benzyl)-amino]-4-methyl-penta-noato-κ,}(1,10-phenanthroline-κ,')nickel(II).

作者信息

Faizi Md Serajul Haque, Dege Necmi, Malinkin Sergey

机构信息

Department of Chemistry, College of Science, Sultan Qaboos University, PO Box 36 Al-Khod 123, Muscat, Sultanate of Oman.

Ondokuz Mayıs University, Arts and Sciences Faculty, Department of Physics, 55139 Atakum-Samsun, Turkey.

出版信息

Acta Crystallogr E Crystallogr Commun. 2017 Aug 30;73(Pt 9):1393-1397. doi: 10.1107/S2056989017012014. eCollection 2017 Sep 1.

Abstract

In the title compound, [Ni(CHNO)(CHN)], the Ni cation shows a distorted octa-hedral coordination environment. It is formed by two N atoms from the phenanthroline ligand, as well as two N and two O atoms belonging to two 2-[(2-hy-droxy-benz-yl)amino]-4-methyl-penta-noate ligands. Complex mol-ecules are connected into layers propagating along the plane hydrogen bonds formed by O atoms of carboxyl-ate and phenoxide groups, which are further connected into a three-dimensional motif.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fe40/5588589/cd81de4d6858/e-73-01393-fig1.jpg

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