Delft University of Technology, Process & Energy Laboratory, Leeghwaterstraat 39, 2628 CB Delft, The Netherlands.
Soft Matter. 2017 Oct 11;13(39):7207-7221. doi: 10.1039/c7sm01204g.
We use simulations to probe the flow properties of dense two-dimensional magnetorheological fluids. Prior results from both experiments and simulations report that the shear stress σ scales with strain rate [small gamma, Greek, dot above] as σ ∼ [small gamma, Greek, dot above], with values of the exponent ranging between 2/3 < Δ ≤ 1. However it remains unclear what properties of the system select the value of Δ, and in particular under what conditions the system displays a yield stress (Δ = 1). To address these questions, we perform simulations of a minimalistic model system in which particles interact via long ranged magnetic dipole forces, finite ranged elastic repulsion, and viscous damping. We find a surprising dependence of the apparent exponent Δ on the form of the viscous force law. For experimentally relevant values of the volume fraction ϕ and the dimensionless Mason number Mn (which quantifies the competition between viscous and magnetic stresses), models using a Stokes-like drag force show Δ ≈ 0.75 and no apparent yield stress. When dissipation occurs at the contact, however, a clear yield stress plateau is evident in the steady state flow curves. In either case, increasing ϕ towards the jamming transition suffices to induce a yield stress. We relate these qualitatively distinct flow curves to clustering mechanisms at the particle scale. For Stokes-like drag, the system builds up anisotropic, chain-like clusters as Mn tends to zero (vanishing strain rate and/or high field strength). For contact damping, by contrast, there is a second clustering mechanism due to inelastic collisions.
我们使用模拟来研究二维稠密磁流变液的流动性质。先前的实验和模拟结果表明,剪切应力 σ 与应变速率 [small gamma, Greek, dot above] 呈比例关系,即 σ∼[small gamma, Greek, dot above],指数 Δ 的值在 2/3<Δ≤1 之间。然而,目前仍不清楚是什么系统特性选择了 Δ 的值,特别是在什么条件下系统会表现出屈服应力(Δ=1)。为了解决这些问题,我们对一个最小模型系统进行了模拟,其中粒子通过长程磁偶极力、有限程弹性斥力和粘性阻尼相互作用。我们发现,表观指数 Δ 与粘性力定律的形式有惊人的依赖关系。对于实验相关的体积分数 ϕ 和无量纲 Mason 数 Mn(量化粘性和磁场应力之间的竞争)值,使用 Stokes 型阻力的模型显示 Δ≈0.75 且没有明显的屈服应力。然而,当耗散发生在接触处时,在稳态流动曲线中可以明显看出屈服应力平台。在这两种情况下,向颗粒堆积过渡增加 ϕ 足以引起屈服应力。我们将这些定性上不同的流动曲线与颗粒尺度上的聚集机制联系起来。对于 Stokes 型阻力,当 Mn 趋于零时(应变速率趋于零和/或场强较高),系统会形成各向异性的链状簇。相比之下,对于接触阻尼,由于非弹性碰撞,存在第二种聚集机制。