School of Materials Science and Engineering, Beijing Institute of Technology , Beijing 100081, China.
National Key Laboratory of Science and Technology on Materials under Shock and Impact , Beijing 100081, China.
ACS Appl Mater Interfaces. 2017 Oct 11;9(40):35444-35452. doi: 10.1021/acsami.7b11034. Epub 2017 Oct 2.
Laser protection for optical components, particularly those in high-power laser systems, has been a major concern. LaSrTiO with its good optical and thermal properties can be potentially applied as a high-temperature optical protective coating or high-reflectivity material for optical components. However, the high-power laser ablation behavior of plasma-sprayed LaSrTiO (x = 0.1) coatings has rarely been investigated. Thus, in this study, laser irradiation experiments were performed to study the effect of high-intensity continuous laser on the ablation behavior of the LaSrTiO coating. The results show that the LaSrTiO coating undergoes three ablation stages during laser irradiation: coating oxidation, formation and growth of new structures (columnar and dendritic crystals), and mechanical failure. A finite-element simulation was also conducted to explore the mechanism of the ablation damage to the LaSrTiO coating and provided a good understanding of the ablation behavior. The apparent ablation characteristics are attributed to the different temperature gradients determined by the reflectivity and thermal diffusivity of the LaSrTiO coating material, which are critical factors for improving the antilaser ablation property. Now, the stainless steel substrate deposited by it can effectively work as a protective shield layer against ablation by laser irradiation.
激光防护光学元件,特别是在高功率激光系统中,一直是一个主要关注点。LaSrTiO 具有良好的光学和热性能,可作为高温光学保护涂层或光学元件的高反射率材料。然而,等离子喷涂 LaSrTiO(x=0.1)涂层的高功率激光烧蚀行为很少被研究。因此,在这项研究中,进行了激光辐照实验来研究高强度连续激光对 LaSrTiO 涂层烧蚀行为的影响。结果表明,LaSrTiO 涂层在激光辐照下经历了三个烧蚀阶段:涂层氧化、新结构(柱状和树枝状晶体)的形成和生长以及机械失效。还进行了有限元模拟,以探讨激光烧蚀对 LaSrTiO 涂层的损伤机制,并提供了对烧蚀行为的良好理解。明显的烧蚀特性归因于由 LaSrTiO 涂层材料的反射率和热扩散率决定的不同温度梯度,这是提高抗激光烧蚀性能的关键因素。现在,沉积在其上的不锈钢基底可以有效地作为激光辐照烧蚀的防护屏蔽层。