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化学圣杯:探究和理解无机离子基质中快速电子/离子耦合输运。

Holy Grails in Chemistry: Investigating and Understanding Fast Electron/Cation Coupled Transport within Inorganic Ionic Matrices.

机构信息

Department of Chemistry, Stony Brook University , Stony Brook, New York 11794, United States.

Department of Materials Science and Engineering, Stony Brook University , Stony Brook, New York 11794, United States.

出版信息

Acc Chem Res. 2017 Mar 21;50(3):544-548. doi: 10.1021/acs.accounts.6b00540.

Abstract

Typically, power and energy are competing concepts in electrochemical energy storage, where one can be optimized only at the expense of the other. However, the specialized and diverse needs of new applications exceed the functional boundaries of existing battery chemistries, where both high power and high energy content are critical. The needed battery paradigms may not be realized by optimization of previous electrochemical energy storage technologies but rather require new basic science breakthroughs involving new materials chemistry. Here we propose that fundamental understanding of electron/cation coupled transport within inorganic ionic matrices is a holy grail that can potentially transform the energy storage landscape.

摘要

通常情况下,在电化学储能中,功率和能量是相互竞争的概念,一方的优化往往是以牺牲另一方为代价的。然而,新应用的特殊和多样化需求超出了现有电池化学的功能边界,在这些应用中,高功率和高能量密度都至关重要。所需的电池模式可能无法通过优化以前的电化学储能技术来实现,而是需要涉及新材料化学的新的基础科学突破。在这里,我们提出,在无机离子基体中,电子/离子耦合输运的基本理解是一个潜在的圣杯,可以彻底改变储能领域。

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