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用于储能的强耦合无机-纳米-碳杂化材料。

Strongly coupled inorganic-nano-carbon hybrid materials for energy storage.

机构信息

Department of Chemistry, Stanford University, Stanford, California 94305, USA.

出版信息

Chem Soc Rev. 2013 Apr 7;42(7):3088-113. doi: 10.1039/c2cs35307e.

Abstract

The global shift of energy production from fossil fuels to renewable energy sources requires more efficient and reliable electrochemical energy storage devices. In particular, the development of electric or hydrogen powered vehicles calls for much-higher-performance batteries, supercapacitors and fuel cells than are currently available. In this review, we present an approach to synthesize electrochemical energy storage materials to form strongly coupled hybrids (SC-hybrids) of inorganic nanomaterials and novel graphitic nano-carbon materials such as carbon nanotubes and graphene, through nucleation and growth of nanoparticles at the functional groups of oxidized graphitic nano-carbon. We show that the inorganic-nano-carbon hybrid materials represent a new approach to synthesize electrode materials with higher electrochemical performance than traditional counterparts made by simple physical mixtures of electrochemically active inorganic particles and conducting carbon materials. The inorganic-nano-carbon hybrid materials are novel due to possible chemical bonding between inorganic nanoparticles and oxidized carbon, affording enhanced charge transport and increased rate capability of electrochemical materials without sacrificing specific capacity. Nano-carbon with various degrees of oxidation provides a novel substrate for nanoparticle nucleation and growth. The interactions between inorganic precursors and oxidized-carbon substrates provide a degree of control over the morphology, size and structure of the resulting inorganic nanoparticles. This paper reviews the recent development of inorganic-nano-carbon hybrid materials for electrochemical energy storage and conversion, including the preparation and functionalization of graphene sheets and carbon nanotubes to impart oxygen containing groups and defects, and methods of synthesis of nanoparticles of various morphologies on oxidized graphene and carbon nanotubes. We then review the applications of the SC-hybrid materials for high performance lithium ion batteries, rechargeable Li-S and Li-O2 batteries, supercapacitors and ultrafast Ni-Fe batteries, and new electrocatalysts for oxygen reduction, oxygen evolution and hydrogen evolution reactions.

摘要

从化石燃料向可再生能源生产的全球能源生产转变需要更高效和可靠的电化学储能设备。特别是,电动或氢能汽车的发展需要比目前可用的电池、超级电容器和燃料电池具有更高性能。在这篇综述中,我们提出了一种合成电化学储能材料的方法,通过在氧化石墨纳米碳的官能团上形成纳米颗粒的成核和生长,将无机纳米材料和新型石墨纳米碳材料(如碳纳米管和石墨烯)合成强耦合的杂化材料(SC-杂化材料)。我们表明,无机-纳米碳杂化材料代表了一种通过简单地将电化学活性无机颗粒和导电碳材料进行物理混合来合成具有比传统材料更高电化学性能的电极材料的新方法。无机-纳米碳杂化材料是新颖的,因为无机纳米颗粒和氧化碳之间可能存在化学键合,从而在不牺牲比容量的情况下提高电荷传输效率和电化学材料的倍率性能。具有不同氧化程度的纳米碳为纳米颗粒的成核和生长提供了新颖的基底。无机前体和氧化碳基底之间的相互作用为控制所得无机纳米颗粒的形态、尺寸和结构提供了一定程度的控制。本文综述了用于电化学储能和转换的无机-纳米碳杂化材料的最新发展,包括氧化石墨烯和碳纳米管的制备和功能化,以赋予含氧基团和缺陷,以及在氧化石墨烯和碳纳米管上合成各种形态纳米颗粒的方法。然后,我们综述了 SC-杂化材料在高性能锂离子电池、可再充电 Li-S 和 Li-O2 电池、超级电容器和超快 Ni-Fe 电池以及用于氧还原、氧析出和析氢反应的新型电催化剂中的应用。

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