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用于生物柴油生产的多换能器声化学反应器中的声化学分析。

Acousto-chemical analysis in multi-transducer sonochemical reactors for biodiesel production.

作者信息

Hussain Mohammed Noorul, Janajreh Isam

机构信息

Department of Mechanical and Materials Engineering, Khalifa University of Science and Technology, Masdar Institute, Abu Dhabi, United Arab Emirates.

Department of Mechanical and Materials Engineering, Khalifa University of Science and Technology, Masdar Institute, Abu Dhabi, United Arab Emirates.

出版信息

Ultrason Sonochem. 2018 Jan;40(Pt A):184-193. doi: 10.1016/j.ultsonch.2017.07.009. Epub 2017 Jul 6.

Abstract

Biodiesel is a powerful alternative fuel that is less polluting and problematic to produce and implement. The production process of biodiesel also gives us the byproduct glycerol, which is a useful feedstock to produce hydrogen and syngas as fuels. With such high value as a fuel we are in need of better production technologies for biodiesel, which is currently being pursued through sonochemical reactors. The development of continuous sonochemical reactors for biodiesel production is a crucial requirement for the biofuel industry. Sonochemical reactors make use of ultrasound and acoustic cavitation to produce biodiesel from waste cooking oils (WCO). In this work we carried out both numerical simulation and experimental analysis of sonochemical reactors with multiple transducers. Through simulation, the effect of double vs a single transducer has been tested for a continuous flow sonochemical reactor. In experimental work three different cases with different ultrasound systems (bath, probe and bath+probe) have been tested. In both the studies, acoustic pressure and biodiesel conversion are analyzed. Results for the simulation show that in shorter reactors, the high cavitation from two transducers dampens the acoustic pressures leading to low conversion. However, at taller heights the effect of combined cavitation is less severe and the acoustic pressure and biodiesel yield are very similar between the designs having single and double transducers. From experiments it was found that the biodiesel conversion depends on several acoustic conditions mainly cavitation. A meticulous and insightful analysis was made to understand the difference in bath type and probe type ultrasound systems on acoustic pressure and biodiesel conversion.

摘要

生物柴油是一种强大的替代燃料,其污染性较小,生产和应用也不存在问题。生物柴油的生产过程还会产生副产品甘油,甘油是生产氢气和合成气作为燃料的有用原料。由于具有如此高的燃料价值,我们需要更好的生物柴油生产技术,目前正在通过声化学反应器来实现这一目标。开发用于生物柴油生产的连续声化学反应器是生物燃料行业的一项关键要求。声化学反应器利用超声波和声空化作用从废食用油(WCO)中生产生物柴油。在这项工作中,我们对具有多个换能器的声化学反应器进行了数值模拟和实验分析。通过模拟,对连续流动声化学反应器中双换能器与单换能器的效果进行了测试。在实验工作中,测试了三种不同的情况,分别采用不同的超声系统(浴式、探头式和浴式+探头式)。在这两项研究中,都对声压和生物柴油转化率进行了分析。模拟结果表明,在较短的反应器中,两个换能器产生的高声空化会降低声压,导致转化率较低。然而,在较高的高度,组合空化的影响不太严重,单换能器和双换能器设计之间的声压和生物柴油产率非常相似。从实验中发现,生物柴油转化率取决于几个声学条件,主要是空化。我们进行了细致而深入的分析,以了解浴式和探头式超声系统在声压和生物柴油转化率方面的差异。

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